Matches in SemOpenAlex for { <https://semopenalex.org/work/W3037367029> ?p ?o ?g. }
- W3037367029 endingPage "5814" @default.
- W3037367029 startingPage "5807" @default.
- W3037367029 abstract "Gas-phase metal clusters have been a subject of research interest for allowing reliable strategies to explore the stability and reactivity of materials at reduced sizes with atomic precision. Here we have prepared well-resolved copper cluster anions Cun– (n = 7–37) and systematically studied their reactivity with O2, NO, and CO. We found remarkable stability of an open-shell cluster Cu18–, which is comparable with the closed-shell clusters Cu17– and Cu19– within the picture of an electronic shell model. Even without having a magic number of valence electrons, intriguingly, the unpaired electron on the singly occupied molecular orbital of Cu18– is mainly contributed by the central copper atom, while the other 18 delocalized valence electrons occupy the lower-energy superatomic orbitals of the cluster. The finding of such an open-shell superatom Cu18–, with an electron configuration of 1S21P61D102S1||1F0, is interesting in the sense that an elementary cluster of coinage metal atoms could still behave as a superatom mimicking coinage metals like silver or gold atoms with an empty f orbital. The superatomic stability of this Cu18– cluster is reinforced by the unique electrostatic interaction between the Cu– core and Cu17 shell, which provides new insights into the chemistry of metal clusters." @default.
- W3037367029 created "2020-07-02" @default.
- W3037367029 creator A5012617304 @default.
- W3037367029 creator A5014795057 @default.
- W3037367029 creator A5038847501 @default.
- W3037367029 creator A5047354060 @default.
- W3037367029 creator A5065115274 @default.
- W3037367029 creator A5068440018 @default.
- W3037367029 date "2020-06-29" @default.
- W3037367029 modified "2023-10-14" @default.
- W3037367029 title "Anionic Copper Clusters Reacting with NO: An Open-Shell Superatom Cu<sub>18</sub><sup>–</sup>" @default.
- W3037367029 cites W1968307836 @default.
- W3037367029 cites W1989191327 @default.
- W3037367029 cites W1994495595 @default.
- W3037367029 cites W2022488634 @default.
- W3037367029 cites W2027583714 @default.
- W3037367029 cites W2029338118 @default.
- W3037367029 cites W2030200666 @default.
- W3037367029 cites W2034629157 @default.
- W3037367029 cites W2037527275 @default.
- W3037367029 cites W2042855774 @default.
- W3037367029 cites W2045216963 @default.
- W3037367029 cites W2049847200 @default.
- W3037367029 cites W2050329175 @default.
- W3037367029 cites W2053439395 @default.
- W3037367029 cites W2053655600 @default.
- W3037367029 cites W2059693256 @default.
- W3037367029 cites W2064517416 @default.
- W3037367029 cites W2077370830 @default.
- W3037367029 cites W2084375945 @default.
- W3037367029 cites W2087555886 @default.
- W3037367029 cites W2094899852 @default.
- W3037367029 cites W2096868202 @default.
- W3037367029 cites W2133141163 @default.
- W3037367029 cites W2136855383 @default.
- W3037367029 cites W2138609803 @default.
- W3037367029 cites W2151078545 @default.
- W3037367029 cites W2313372478 @default.
- W3037367029 cites W2314143187 @default.
- W3037367029 cites W2323712420 @default.
- W3037367029 cites W2329082285 @default.
- W3037367029 cites W2330573181 @default.
- W3037367029 cites W2339752187 @default.
- W3037367029 cites W2557838702 @default.
- W3037367029 cites W2586848426 @default.
- W3037367029 cites W2615828339 @default.
- W3037367029 cites W2659598858 @default.
- W3037367029 cites W2806250317 @default.
- W3037367029 cites W2806394448 @default.
- W3037367029 cites W2908265108 @default.
- W3037367029 cites W2924795774 @default.
- W3037367029 cites W2955452014 @default.
- W3037367029 cites W2956116903 @default.
- W3037367029 cites W2980388208 @default.
- W3037367029 cites W4211231377 @default.
- W3037367029 doi "https://doi.org/10.1021/acs.jpclett.0c01643" @default.
- W3037367029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32597656" @default.
- W3037367029 hasPublicationYear "2020" @default.
- W3037367029 type Work @default.
- W3037367029 sameAs 3037367029 @default.
- W3037367029 citedByCount "19" @default.
- W3037367029 countsByYear W30373670292020 @default.
- W3037367029 countsByYear W30373670292021 @default.
- W3037367029 countsByYear W30373670292022 @default.
- W3037367029 countsByYear W30373670292023 @default.
- W3037367029 crossrefType "journal-article" @default.
- W3037367029 hasAuthorship W3037367029A5012617304 @default.
- W3037367029 hasAuthorship W3037367029A5014795057 @default.
- W3037367029 hasAuthorship W3037367029A5038847501 @default.
- W3037367029 hasAuthorship W3037367029A5047354060 @default.
- W3037367029 hasAuthorship W3037367029A5065115274 @default.
- W3037367029 hasAuthorship W3037367029A5068440018 @default.
- W3037367029 hasConcept C11916219 @default.
- W3037367029 hasConcept C121332964 @default.
- W3037367029 hasConcept C139358910 @default.
- W3037367029 hasConcept C145148216 @default.
- W3037367029 hasConcept C147120987 @default.
- W3037367029 hasConcept C147597530 @default.
- W3037367029 hasConcept C159467904 @default.
- W3037367029 hasConcept C164866538 @default.
- W3037367029 hasConcept C168900304 @default.
- W3037367029 hasConcept C171706072 @default.
- W3037367029 hasConcept C178790620 @default.
- W3037367029 hasConcept C184779094 @default.
- W3037367029 hasConcept C185592680 @default.
- W3037367029 hasConcept C186927785 @default.
- W3037367029 hasConcept C189394030 @default.
- W3037367029 hasConcept C198291218 @default.
- W3037367029 hasConcept C199360897 @default.
- W3037367029 hasConcept C32909587 @default.
- W3037367029 hasConcept C37649677 @default.
- W3037367029 hasConcept C38649801 @default.
- W3037367029 hasConcept C41008148 @default.
- W3037367029 hasConcept C539548551 @default.
- W3037367029 hasConcept C544153396 @default.
- W3037367029 hasConcept C544778455 @default.
- W3037367029 hasConcept C62520636 @default.
- W3037367029 hasConcept C70050531 @default.