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- W3037367159 endingPage "121544" @default.
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- W3037367159 abstract "A water-stable 3D porous Gd-based MOF decorated by hydroxyl groups with irl topology, {[Gd2(OH-BDC)2(DMF)2(H2O)2]∙(H2O)}n (1) (OH–H2BDC = 2,5-dihydroxyterephthalic acid, DMF = dimethylformamide) has been prepared and were structurally characterized. The results of TGA and PXRD revealed that 1 shows high thermal stability up to 350 °C and good water stability. 1 exhibits a 3D framework with 1D channel of 8.4 × 8.1 Å2 parallel to the c axis. Activated 1 (1a) shows an 5-Fluorouracil payload of 23.2 wt% and higher signal enhancement ability than Gd-DTPA with the r1 value being 31.20 mM−1 S−1. Meanwhile, 1a exhibits selective CO2 uptake compare with CH4, N2, O2, and H2 at room temperature under simulation condition. Furthermore, the magnetic property, in vitro MTT assays and in vivo Zebrafish toxicity tests of 1 have also been carried out." @default.
- W3037367159 created "2020-07-02" @default.
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- W3037367159 date "2020-09-01" @default.
- W3037367159 modified "2023-09-26" @default.
- W3037367159 title "A hydroxyl-functionalized 3D porous gadolinium-organic framework platform for drug delivery, imaging and gas separation" @default.
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- W3037367159 doi "https://doi.org/10.1016/j.jssc.2020.121544" @default.
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