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- W3037422531 endingPage "2512" @default.
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- W3037422531 abstract "Abstract Poly(2‐arylazulene‐ alt ‐fluorene) and poly(2‐arylazulene‐ alt ‐thiophene) are synthesized via Suzuki and Stille cross‐coupling polymerization, respectively, using 1,3‐dibromo‐2‐arylazulenes as monomers, which are prepared by a novel directed C−H activation method of 2‐carboxylic azulene and subsequent bromination reaction. Our study shows that functionalization at the 2‐position of azulene monomers influences polymer properties. For instance, different from electron‐withdrawing groups that discourage the protonation of azulene, electron‐donating aryl groups, however, enhances the sensitivity of response to acid. Protonation of the polymers leads to significant shifts in absorption spectra accompanying with obvious color changes from green to brown in majority cases because of the formation of poly(azulenium cation). The electrochromic properties of polymers are examined, exhibiting that nature of aryl group at the 2‐position of azulene influences the stability of their electrochromic devices." @default.
- W3037422531 created "2020-07-02" @default.
- W3037422531 creator A5007813530 @default.
- W3037422531 creator A5058504654 @default.
- W3037422531 date "2020-07-07" @default.
- W3037422531 modified "2023-09-25" @default.
- W3037422531 title "Modulating the Properties of Azulene‐containing Polymers Through Functionalization at the 2‐Position of Azulene" @default.
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- W3037422531 doi "https://doi.org/10.1002/asia.202000627" @default.
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