FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3037475314> ?p ?o ?g. }

• W3037475314 endingPage "408" @default.
• W3037475314 startingPage "400" @default.
• W3037475314 abstract "Hydrogen peroxide is considered one of the most important commodity chemicals worldwide but its main production method, the anthraquinone process, poses serious logistical, environmental and safety challenges. Electrocatalytic synthesis through the reduction of molecular oxygen is a promising H2O2 production route. However, the reduction of molecular oxygen is kinetically hindered and stable electrocatalysts with a high activity and selectivity towards the 2-electron transfer reaction are needed. In this work, we evaluated the influence of chloride on catalysts with low palladium loadings on the ORR selectivity towards H2O2. We report the factors and dynamics that influence H2O2 production and highlight synthesis strategies to obtain close to 100% selectivity. By probing the electrode surface after various degradation cycles, we evaluate the role of adsorbing species and the catalysts oxidation states on the hydrogen peroxide selectivity. We systematically modified the catalyst synthesis using different Pd-precursors that were reduced and supported on high surface area graphene nanoribbons. Identical location transmission electron microscopy was used to probe catalyst dynamics during reaction and the activities and selectivities were measured by a rotating ring disk electrode. We probe the potential boundary conditions that lead to catalyst degradation during accelerated stress tests and potentiostatic polarisation and demonstrate how the catalytically active surface can be revived after degradation. The obtained insights can be used as guideline for the development of active, selective and stable catalysts with low noble metal loadings." @default.
• W3037475314 created "2020-07-02" @default.
• W3037475314 creator A5000615181 @default.
• W3037475314 creator A5002899488 @default.
• W3037475314 creator A5018906660 @default.
• W3037475314 creator A5033543476 @default.
• W3037475314 creator A5044793501 @default.
• W3037475314 creator A5050336219 @default.
• W3037475314 creator A5053735446 @default.
• W3037475314 creator A5055974229 @default.
• W3037475314 creator A5065682352 @default.
• W3037475314 date "2020-09-01" @default.
• W3037475314 modified "2023-10-10" @default.
• W3037475314 title "The oxygen reduction reaction on palladium with low metal loadings: The effects of chlorides on the stability and activity towards hydrogen peroxide" @default.
• W3037475314 cites W1967178329 @default.
• W3037475314 cites W1969591366 @default.
• W3037475314 cites W1972243282 @default.
• W3037475314 cites W1975936460 @default.
• W3037475314 cites W1980725075 @default.
• W3037475314 cites W1982976486 @default.
• W3037475314 cites W1986046581 @default.
• W3037475314 cites W1996419313 @default.
• W3037475314 cites W2004476303 @default.
• W3037475314 cites W2028099496 @default.
• W3037475314 cites W2039527261 @default.
• W3037475314 cites W2044329234 @default.
• W3037475314 cites W2045044343 @default.
• W3037475314 cites W2045703010 @default.
• W3037475314 cites W2050240027 @default.
• W3037475314 cites W2055554173 @default.
• W3037475314 cites W2056306182 @default.
• W3037475314 cites W2056373626 @default.
• W3037475314 cites W2058497727 @default.
• W3037475314 cites W2061367556 @default.
• W3037475314 cites W2062589468 @default.
• W3037475314 cites W2062883797 @default.
• W3037475314 cites W2066084708 @default.
• W3037475314 cites W2066084830 @default.
• W3037475314 cites W2068722571 @default.
• W3037475314 cites W2077228582 @default.
• W3037475314 cites W2083274401 @default.
• W3037475314 cites W2087207644 @default.
• W3037475314 cites W2090277589 @default.
• W3037475314 cites W2095252998 @default.
• W3037475314 cites W2110534188 @default.
• W3037475314 cites W2120124901 @default.
• W3037475314 cites W2125863915 @default.
• W3037475314 cites W2135031573 @default.
• W3037475314 cites W2169981063 @default.
• W3037475314 cites W2320907518 @default.
• W3037475314 cites W2344546478 @default.
• W3037475314 cites W2394699830 @default.
• W3037475314 cites W2469626605 @default.
• W3037475314 cites W2474773075 @default.
• W3037475314 cites W2547008990 @default.
• W3037475314 cites W2581619212 @default.
• W3037475314 cites W2584333491 @default.
• W3037475314 cites W2600707316 @default.
• W3037475314 cites W2736075177 @default.
• W3037475314 cites W2765837773 @default.
• W3037475314 cites W2784667586 @default.
• W3037475314 cites W2795293472 @default.
• W3037475314 cites W2810165469 @default.
• W3037475314 cites W2891982331 @default.
• W3037475314 cites W2950889169 @default.
• W3037475314 cites W2951356883 @default.
• W3037475314 cites W3131685164 @default.
• W3037475314 cites W402333284 @default.
• W3037475314 doi "https://doi.org/10.1016/j.jcat.2020.06.019" @default.
• W3037475314 hasPublicationYear "2020" @default.
• W3037475314 type Work @default.
• W3037475314 sameAs 3037475314 @default.
• W3037475314 citedByCount "22" @default.
• W3037475314 countsByYear W30374753142020 @default.
• W3037475314 countsByYear W30374753142021 @default.
• W3037475314 countsByYear W30374753142022 @default.
• W3037475314 countsByYear W30374753142023 @default.
• W3037475314 crossrefType "journal-article" @default.
• W3037475314 hasAuthorship W3037475314A5000615181 @default.
• W3037475314 hasAuthorship W3037475314A5002899488 @default.
• W3037475314 hasAuthorship W3037475314A5018906660 @default.
• W3037475314 hasAuthorship W3037475314A5033543476 @default.
• W3037475314 hasAuthorship W3037475314A5044793501 @default.
• W3037475314 hasAuthorship W3037475314A5050336219 @default.
• W3037475314 hasAuthorship W3037475314A5053735446 @default.
• W3037475314 hasAuthorship W3037475314A5055974229 @default.
• W3037475314 hasAuthorship W3037475314A5065682352 @default.
• W3037475314 hasBestOaLocation W30374753142 @default.
• W3037475314 hasConcept C118792377 @default.
• W3037475314 hasConcept C127413603 @default.
• W3037475314 hasConcept C161790260 @default.
• W3037475314 hasConcept C178790620 @default.
• W3037475314 hasConcept C179104552 @default.
• W3037475314 hasConcept C185592680 @default.
• W3037475314 hasConcept C2775871042 @default.
• W3037475314 hasConcept C42360764 @default.
• W3037475314 hasConcept C502130503 @default.
• W3037475314 hasConcept C533411734 @default.

• next