Matches in SemOpenAlex for { <https://semopenalex.org/work/W3037530323> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W3037530323 endingPage "4266" @default.
- W3037530323 startingPage "4266" @default.
- W3037530323 abstract "Estimating molar solubility from the Hildebrand-Scott relation employing Hansen solubility parameters (HSP) is widely presumed a valid semi-quantitative approach. To test this presumption and to determine quantitatively the inherent accuracy of such a solubility prognosis, l-ascorbic acid (LAA) was treated as an example of a commercially important solute. Analytical calculus and Monte Carlo (MC) simulation were performed for 20 common solvents with total HSP ranging from 14.5 to 33.0 (MPa)0.5 utilizing validated material data. It was found that, due to the uncertainty of the material data used in the calculations, the solubility prediction had a large scattering and, thus, a low precision. Prediction power is most adversely affected by the uncertainty of the HSP estimates (solvent and solute), followed by the solute heat of fusion. The solute melting temperature and molar volume have minor effects. Computed and experimental solubilities show the same qualitative behavior, while quantitative discrepancies reach one to three orders of magnitude. Solubility estimates were found to provide, at best, rough guiding information but, with the quality of material data on LAA available, they cannot be rated semi-quantitative. It is assumed that these results generally apply at least to solute-solvent systems with a material data quality and solubility similar to LAA." @default.
- W3037530323 created "2020-07-02" @default.
- W3037530323 creator A5048164711 @default.
- W3037530323 creator A5077103056 @default.
- W3037530323 date "2020-06-22" @default.
- W3037530323 modified "2023-10-16" @default.
- W3037530323 title "Accuracy of Molar Solubility Prediction from Hansen Parameters. An Exemplified Treatment of the Bioantioxidant l-Ascorbic Acid" @default.
- W3037530323 cites W1977224150 @default.
- W3037530323 cites W1981078983 @default.
- W3037530323 cites W1984516093 @default.
- W3037530323 cites W1999534771 @default.
- W3037530323 cites W2016043004 @default.
- W3037530323 cites W2017321332 @default.
- W3037530323 cites W2025731804 @default.
- W3037530323 cites W2039444097 @default.
- W3037530323 cites W2040275100 @default.
- W3037530323 cites W2042183767 @default.
- W3037530323 cites W2072969944 @default.
- W3037530323 cites W2090696136 @default.
- W3037530323 cites W2091931635 @default.
- W3037530323 cites W2092449571 @default.
- W3037530323 cites W2126427823 @default.
- W3037530323 cites W2744254210 @default.
- W3037530323 cites W2751960609 @default.
- W3037530323 cites W2766659697 @default.
- W3037530323 cites W2790333994 @default.
- W3037530323 doi "https://doi.org/10.3390/app10124266" @default.
- W3037530323 hasPublicationYear "2020" @default.
- W3037530323 type Work @default.
- W3037530323 sameAs 3037530323 @default.
- W3037530323 citedByCount "1" @default.
- W3037530323 countsByYear W30375303232023 @default.
- W3037530323 crossrefType "journal-article" @default.
- W3037530323 hasAuthorship W3037530323A5048164711 @default.
- W3037530323 hasAuthorship W3037530323A5077103056 @default.
- W3037530323 hasBestOaLocation W30375303231 @default.
- W3037530323 hasConcept C100293340 @default.
- W3037530323 hasConcept C105795698 @default.
- W3037530323 hasConcept C121332964 @default.
- W3037530323 hasConcept C155574463 @default.
- W3037530323 hasConcept C178790620 @default.
- W3037530323 hasConcept C185592680 @default.
- W3037530323 hasConcept C192562407 @default.
- W3037530323 hasConcept C19499675 @default.
- W3037530323 hasConcept C2780471494 @default.
- W3037530323 hasConcept C2986274086 @default.
- W3037530323 hasConcept C31903555 @default.
- W3037530323 hasConcept C33923547 @default.
- W3037530323 hasConcept C97355855 @default.
- W3037530323 hasConceptScore W3037530323C100293340 @default.
- W3037530323 hasConceptScore W3037530323C105795698 @default.
- W3037530323 hasConceptScore W3037530323C121332964 @default.
- W3037530323 hasConceptScore W3037530323C155574463 @default.
- W3037530323 hasConceptScore W3037530323C178790620 @default.
- W3037530323 hasConceptScore W3037530323C185592680 @default.
- W3037530323 hasConceptScore W3037530323C192562407 @default.
- W3037530323 hasConceptScore W3037530323C19499675 @default.
- W3037530323 hasConceptScore W3037530323C2780471494 @default.
- W3037530323 hasConceptScore W3037530323C2986274086 @default.
- W3037530323 hasConceptScore W3037530323C31903555 @default.
- W3037530323 hasConceptScore W3037530323C33923547 @default.
- W3037530323 hasConceptScore W3037530323C97355855 @default.
- W3037530323 hasIssue "12" @default.
- W3037530323 hasLocation W30375303231 @default.
- W3037530323 hasLocation W30375303232 @default.
- W3037530323 hasLocation W30375303233 @default.
- W3037530323 hasOpenAccess W3037530323 @default.
- W3037530323 hasPrimaryLocation W30375303231 @default.
- W3037530323 hasRelatedWork W2027749248 @default.
- W3037530323 hasRelatedWork W2089793644 @default.
- W3037530323 hasRelatedWork W2113305108 @default.
- W3037530323 hasRelatedWork W2149895702 @default.
- W3037530323 hasRelatedWork W2183559753 @default.
- W3037530323 hasRelatedWork W2209927890 @default.
- W3037530323 hasRelatedWork W2363891901 @default.
- W3037530323 hasRelatedWork W2377301636 @default.
- W3037530323 hasRelatedWork W2382522809 @default.
- W3037530323 hasRelatedWork W4288842484 @default.
- W3037530323 hasVolume "10" @default.
- W3037530323 isParatext "false" @default.
- W3037530323 isRetracted "false" @default.
- W3037530323 magId "3037530323" @default.
- W3037530323 workType "article" @default.