Matches in SemOpenAlex for { <https://semopenalex.org/work/W3037636063> ?p ?o ?g. }
- W3037636063 endingPage "2461" @default.
- W3037636063 startingPage "2456" @default.
- W3037636063 abstract "Polycyclic aromatic hydrocarbons consisting of three fused anthracene units were designed as new π-conjugated compounds having helical structures. These expanded helicenes were synthesized by Pt-catalyzed cycloisomerization of the corresponding ethynyl-substituted precursors. The nonplanar and helical structure was confirmed by X-ray analysis and DFT calculations, and the barrier to helical inversion was estimated to be 34 kJ mol−1. The enantiomers of the diphenyl derivative were successfully resolved by chiral HPLC. Enantiopure samples showed good chiroptical performance in the CD (|Δϵ| 1380 L mol−1 cm−1) and CPL (|glum| 0.013) spectra, and these values were considerably large for simple organic molecules. The unique chiroptical properties are discussed on the basis of the molecular structure and the electronic state with the aid of time-dependent DFT calculations." @default.
- W3037636063 created "2020-07-02" @default.
- W3037636063 creator A5036090286 @default.
- W3037636063 creator A5041288783 @default.
- W3037636063 creator A5043887773 @default.
- W3037636063 creator A5061930920 @default.
- W3037636063 creator A5062534701 @default.
- W3037636063 creator A5063383002 @default.
- W3037636063 date "2020-07-10" @default.
- W3037636063 modified "2023-10-16" @default.
- W3037636063 title "Multiple Fused Anthracenes as Helical Polycyclic Aromatic Hydrocarbon Motif for Chiroptical Performance Enhancement" @default.
- W3037636063 cites W1596353367 @default.
- W3037636063 cites W1850985045 @default.
- W3037636063 cites W1970347475 @default.
- W3037636063 cites W1997236222 @default.
- W3037636063 cites W1998647414 @default.
- W3037636063 cites W2004927411 @default.
- W3037636063 cites W2007731282 @default.
- W3037636063 cites W2012206068 @default.
- W3037636063 cites W2012331842 @default.
- W3037636063 cites W2012823538 @default.
- W3037636063 cites W2018521701 @default.
- W3037636063 cites W2023401537 @default.
- W3037636063 cites W2024189026 @default.
- W3037636063 cites W2039778042 @default.
- W3037636063 cites W2042915585 @default.
- W3037636063 cites W2047735309 @default.
- W3037636063 cites W2054393238 @default.
- W3037636063 cites W2054996528 @default.
- W3037636063 cites W2083905668 @default.
- W3037636063 cites W2087123231 @default.
- W3037636063 cites W2105704430 @default.
- W3037636063 cites W2114411459 @default.
- W3037636063 cites W2124528111 @default.
- W3037636063 cites W2144459212 @default.
- W3037636063 cites W2146469557 @default.
- W3037636063 cites W2166032823 @default.
- W3037636063 cites W2175728713 @default.
- W3037636063 cites W2227401072 @default.
- W3037636063 cites W2313017771 @default.
- W3037636063 cites W2316988243 @default.
- W3037636063 cites W2330218484 @default.
- W3037636063 cites W2333827620 @default.
- W3037636063 cites W2524061522 @default.
- W3037636063 cites W2606034902 @default.
- W3037636063 cites W2621190651 @default.
- W3037636063 cites W2750766948 @default.
- W3037636063 cites W2766222998 @default.
- W3037636063 cites W2768988661 @default.
- W3037636063 cites W2769330854 @default.
- W3037636063 cites W2773877005 @default.
- W3037636063 cites W2789720320 @default.
- W3037636063 cites W2790011620 @default.
- W3037636063 cites W2799511069 @default.
- W3037636063 cites W2800061612 @default.
- W3037636063 cites W2810547861 @default.
- W3037636063 cites W2892285310 @default.
- W3037636063 cites W2893074513 @default.
- W3037636063 cites W2898038662 @default.
- W3037636063 cites W2901137056 @default.
- W3037636063 cites W2903819258 @default.
- W3037636063 cites W2922272498 @default.
- W3037636063 cites W2946144433 @default.
- W3037636063 cites W2970658599 @default.
- W3037636063 cites W2984836520 @default.
- W3037636063 cites W4233162946 @default.
- W3037636063 cites W4241841929 @default.
- W3037636063 cites W4242857460 @default.
- W3037636063 cites W4243309513 @default.
- W3037636063 cites W4250429479 @default.
- W3037636063 cites W4253748988 @default.
- W3037636063 cites W4254614487 @default.
- W3037636063 doi "https://doi.org/10.1002/asia.202000394" @default.
- W3037636063 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32573111" @default.
- W3037636063 hasPublicationYear "2020" @default.
- W3037636063 type Work @default.
- W3037636063 sameAs 3037636063 @default.
- W3037636063 citedByCount "21" @default.
- W3037636063 countsByYear W30376360632020 @default.
- W3037636063 countsByYear W30376360632021 @default.
- W3037636063 countsByYear W30376360632022 @default.
- W3037636063 countsByYear W30376360632023 @default.
- W3037636063 crossrefType "journal-article" @default.
- W3037636063 hasAuthorship W3037636063A5036090286 @default.
- W3037636063 hasAuthorship W3037636063A5041288783 @default.
- W3037636063 hasAuthorship W3037636063A5043887773 @default.
- W3037636063 hasAuthorship W3037636063A5061930920 @default.
- W3037636063 hasAuthorship W3037636063A5062534701 @default.
- W3037636063 hasAuthorship W3037636063A5063383002 @default.
- W3037636063 hasConcept C112613896 @default.
- W3037636063 hasConcept C133571119 @default.
- W3037636063 hasConcept C146686406 @default.
- W3037636063 hasConcept C147597530 @default.
- W3037636063 hasConcept C161790260 @default.
- W3037636063 hasConcept C178790620 @default.
- W3037636063 hasConcept C185592680 @default.
- W3037636063 hasConcept C2779033964 @default.
- W3037636063 hasConcept C2779563022 @default.