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- W3037721445 abstract "Differential scanning calorimetry has been employed to investigate the thermal properties of Se 80 Te 15-x Cd 5 Bi x (x = 0, 5, 10) glass system. The Variation of characteristic temperatures such as glass transition temperature (T g ), onset crystallization temperature (T c ), peak crystallization temperature (T p ) and melting temperature (T m ) are studied as a function of composition and heating rate. A stepwise increase in values of characteristic temperatures has been observed with the increase in heating rate. Further, obtained values of characteristic temperatures display decreasing trend with increase in bismuth concentration. The compositional and heating rate dependence of Thermal parameters such as glass forming ability (ΔT), thermal stability (H g ), enthalpy (ΔH) and entropy (ΔS) has been investigated. It has been observed that ΔT and H g have lowest and highest values for Se 80 Te 5 Cd 5 Bi 10 and Se 80 Te 15 Cd 5 compositions respectively. Avrami index (n) and activation energy for crystallization (E c ) have been calculated for all the samples. Values of n obtained for Se 80 Te 15 Cd 5 , Se 80 Te 15 Cd 5 Bi 5 and Se 80 Te 5 Cd 5 Bi 10 compositions are found to be 1.44, 2.16 and 2.16 respectively. Based on the obtained values of n, the nucleation process in alloys is discussed. It is noteworthy to mention that least value of Ec is observed for the alloy Se 80 Te 5 Cd 5 Bi 10 containing the highest amount of bismuth. Furthermore, calculated thermal parameters are used to anticipate the electrical switching behavior of the alloys." @default.
- W3037721445 created "2020-07-02" @default.
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- W3037721445 date "2020-11-01" @default.
- W3037721445 modified "2023-09-24" @default.
- W3037721445 title "Effect of bismuth incorporation on thermal properties of quaternary chalcogenide glass Se80Te15-xCd5Bix (x=0,5,10) alloys" @default.
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- W3037721445 doi "https://doi.org/10.1016/j.ceramint.2020.06.269" @default.
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