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• W3037914229 abstract "We report a palladium-catalyzed, three-component carbosilylation reaction of internal symmetrical alkynes, silicon electrophiles, and primary alkyl zinc iodides. Depending on the choice of ligand, stereoselective synthesis of either cis- or trans-tetrasubstituted vinyl silanes is possible. We also demonstrate conditions for the Hiyama cross-coupling of these products to prepare geometrically defined tetrasubstituted alkenes." @default.
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• W3037914229 date "2020-06-24" @default.
• W3037914229 modified "2023-10-13" @default.
• W3037914229 title "Stereoselective Synthesis of <i>Cis</i>- and <i>Trans</i>-Tetrasubstituted Vinyl Silanes Using a Silyl-Heck Strategy and Hiyama Conditions for Their Cross-Coupling" @default.
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• W3037914229 doi "https://doi.org/10.1021/jacs.0c05382" @default.
• W3037914229 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7405989" @default.
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