Matches in SemOpenAlex for { <https://semopenalex.org/work/W3037978056> ?p ?o ?g. }
- W3037978056 endingPage "133" @default.
- W3037978056 startingPage "123" @default.
- W3037978056 abstract "Understanding the process of water oxidation, especially intermediate species, represents an important step toward gaining a mechanistic understanding of new emerging catalysts. The aim of this study is exploring the process of water oxidation and electrolyte orientation under external potential when using an emerging water oxidation catalyst, CoB i , in sodium borate (NaBi) buffer using in situ attenuated–total-reflection Fourier transform infrared spectroscopy (ATR-FTIR) spectroscopy. CoB i is generated via electrodeposition from aqueous solutions containing borate and Co 2+ . IR spectra were obtained for CoB i films under applied potentials supporting water oxidation catalysis. The spectra of water and CoB i on ZnSe/Cr/Au electrode surfaces change in intensity and their slope depends on the potential, which is rarely reported. The appearance of new bands at certain potentials is interpreted in terms of the potential-dependent re-alignment of water and borate molecules both from the film and electrolyte. A superoxide surface intermediate at 1027 cm -1 was observed in both thin and thick films. It is proposed to be Co (III)OO*H bridging and relates to a fast water oxidation process. The chemical structure of the intermediate species is proposed finally." @default.
- W3037978056 created "2020-07-02" @default.
- W3037978056 creator A5044329977 @default.
- W3037978056 creator A5048966194 @default.
- W3037978056 creator A5054009756 @default.
- W3037978056 creator A5068195942 @default.
- W3037978056 date "2020-06-01" @default.
- W3037978056 modified "2023-10-15" @default.
- W3037978056 title "<i>In Situ</i> ATR Infrared Study of Cobalt-Borate Water Oxidation Catalysts" @default.
- W3037978056 cites W1841829164 @default.
- W3037978056 cites W1963597613 @default.
- W3037978056 cites W1971634438 @default.
- W3037978056 cites W1979338410 @default.
- W3037978056 cites W1982446643 @default.
- W3037978056 cites W1986783341 @default.
- W3037978056 cites W2004670138 @default.
- W3037978056 cites W2020080291 @default.
- W3037978056 cites W2026788985 @default.
- W3037978056 cites W2036965740 @default.
- W3037978056 cites W2039785035 @default.
- W3037978056 cites W2043396906 @default.
- W3037978056 cites W2047441815 @default.
- W3037978056 cites W2048252048 @default.
- W3037978056 cites W2050714979 @default.
- W3037978056 cites W2053763231 @default.
- W3037978056 cites W2056426718 @default.
- W3037978056 cites W2057855777 @default.
- W3037978056 cites W2058267335 @default.
- W3037978056 cites W2058669530 @default.
- W3037978056 cites W2058677101 @default.
- W3037978056 cites W2075018177 @default.
- W3037978056 cites W2082584922 @default.
- W3037978056 cites W2085141418 @default.
- W3037978056 cites W2089757050 @default.
- W3037978056 cites W2114291507 @default.
- W3037978056 cites W2132922089 @default.
- W3037978056 cites W2152421973 @default.
- W3037978056 cites W2155835657 @default.
- W3037978056 cites W2159782108 @default.
- W3037978056 cites W2161452689 @default.
- W3037978056 cites W2161680210 @default.
- W3037978056 cites W2163337934 @default.
- W3037978056 cites W2172236987 @default.
- W3037978056 cites W2316068981 @default.
- W3037978056 cites W2316184536 @default.
- W3037978056 cites W2321284911 @default.
- W3037978056 cites W2331154424 @default.
- W3037978056 cites W2342359684 @default.
- W3037978056 cites W2506756537 @default.
- W3037978056 cites W2612163852 @default.
- W3037978056 cites W2746217841 @default.
- W3037978056 cites W2765985644 @default.
- W3037978056 cites W2766006920 @default.
- W3037978056 cites W2788390711 @default.
- W3037978056 cites W2908848170 @default.
- W3037978056 cites W2920101140 @default.
- W3037978056 cites W2923100840 @default.
- W3037978056 cites W3103072450 @default.
- W3037978056 doi "https://doi.org/10.4028/www.scientific.net/msf.998.123" @default.
- W3037978056 hasPublicationYear "2020" @default.
- W3037978056 type Work @default.
- W3037978056 sameAs 3037978056 @default.
- W3037978056 citedByCount "3" @default.
- W3037978056 countsByYear W30379780562021 @default.
- W3037978056 countsByYear W30379780562022 @default.
- W3037978056 countsByYear W30379780562023 @default.
- W3037978056 crossrefType "journal-article" @default.
- W3037978056 hasAuthorship W3037978056A5044329977 @default.
- W3037978056 hasAuthorship W3037978056A5048966194 @default.
- W3037978056 hasAuthorship W3037978056A5054009756 @default.
- W3037978056 hasAuthorship W3037978056A5068195942 @default.
- W3037978056 hasBestOaLocation W30379780562 @default.
- W3037978056 hasConcept C127413603 @default.
- W3037978056 hasConcept C147789679 @default.
- W3037978056 hasConcept C153642686 @default.
- W3037978056 hasConcept C160892712 @default.
- W3037978056 hasConcept C161790260 @default.
- W3037978056 hasConcept C17525397 @default.
- W3037978056 hasConcept C178790620 @default.
- W3037978056 hasConcept C179104552 @default.
- W3037978056 hasConcept C184651966 @default.
- W3037978056 hasConcept C185592680 @default.
- W3037978056 hasConcept C192562407 @default.
- W3037978056 hasConcept C2777822432 @default.
- W3037978056 hasConcept C42360764 @default.
- W3037978056 hasConcept C49102809 @default.
- W3037978056 hasConcept C501308230 @default.
- W3037978056 hasConcept C515602321 @default.
- W3037978056 hasConcept C52859227 @default.
- W3037978056 hasConcept C68801617 @default.
- W3037978056 hasConceptScore W3037978056C127413603 @default.
- W3037978056 hasConceptScore W3037978056C147789679 @default.
- W3037978056 hasConceptScore W3037978056C153642686 @default.
- W3037978056 hasConceptScore W3037978056C160892712 @default.
- W3037978056 hasConceptScore W3037978056C161790260 @default.
- W3037978056 hasConceptScore W3037978056C17525397 @default.
- W3037978056 hasConceptScore W3037978056C178790620 @default.
- W3037978056 hasConceptScore W3037978056C179104552 @default.