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- W3038093147 abstract "Abstract The first colloidal nanoparticle synthesis of the copper selenophosphate Cu 3 PSe 4 , a promising new material for photovoltaics, is reported. Because the formation of binary copper selenide impurities seemed to form more readily, two approaches were developed to install phosphorus bonds directly: 1) the synthesis of molecular P 4 Se 3 and subsequent reaction with a copper precursor, (P‐Se)+Cu, and 2) the synthesis of copper phosphide, Cu 3 P, nanoparticles and subsequent reaction with a selenium precursor, (Cu‐P)+Se. The isolation and purification of Cu 3 P nanoparticles and subsequent selenization yielded phase‐pure Cu 3 PSe 4 . Solvent effects and Se precursor reactivities were elucidated and were key to understanding the final reaction conditions." @default.
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- W3038093147 date "2020-01-09" @default.
- W3038093147 modified "2023-10-01" @default.
- W3038093147 title "A Directed Route to Colloidal Nanoparticle Synthesis of the Copper Selenophosphate Cu <sub>3</sub> PSe <sub>4</sub>" @default.
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- W3038093147 doi "https://doi.org/10.1002/ange.201911385" @default.
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