Matches in SemOpenAlex for { <https://semopenalex.org/work/W3038108596> ?p ?o ?g. }
- W3038108596 endingPage "17606" @default.
- W3038108596 startingPage "17600" @default.
- W3038108596 abstract "Abstract To gain insight into chiral recognition in porous materials we have prepared a family of fourth generation chiral metal–organic frameworks (MOFs) that have rigid frameworks and adaptable (flexible) pores. The previously reported parent material, [Co 2 (S‐mandelate) 2 (4,4′‐bipyridine) 3 ](NO 3 ) 2 , CMOM‐ 1S , is a modular MOF; five new variants in which counterions (BF 4 − , CMOM‐ 2S ) or mandelate ligands are substituted (2‐Cl, CMOM‐ 11R ; 3‐Cl, CMOM‐ 21R ; 4‐Cl, CMOM‐ 31R ; 4‐CH 3 , CMOM‐ 41R ) and the existing CF 3 SO 3 − variant CMOM‐ 3S are studied herein. Fine‐tuning of pore size, shape, and chemistry afforded a series of distinct host–guest binding sites with variable chiral separation properties with respect to three structural isomers of phenylpropanol. Structural analysis of the resulting crystalline sponge phases revealed that host–guest interactions, guest–guest interactions, and pore adaptability collectively determine chiral discrimination." @default.
- W3038108596 created "2020-07-02" @default.
- W3038108596 creator A5001382768 @default.
- W3038108596 creator A5044900607 @default.
- W3038108596 creator A5081651773 @default.
- W3038108596 date "2020-08-11" @default.
- W3038108596 modified "2023-10-18" @default.
- W3038108596 title "Structural Elucidation of the Mechanism of Molecular Recognition in Chiral Crystalline Sponges" @default.
- W3038108596 cites W1611493559 @default.
- W3038108596 cites W1967401337 @default.
- W3038108596 cites W1967819346 @default.
- W3038108596 cites W1971899363 @default.
- W3038108596 cites W1972646318 @default.
- W3038108596 cites W1977770232 @default.
- W3038108596 cites W1978475337 @default.
- W3038108596 cites W1983962819 @default.
- W3038108596 cites W1986011000 @default.
- W3038108596 cites W1996901909 @default.
- W3038108596 cites W2004235923 @default.
- W3038108596 cites W2012488984 @default.
- W3038108596 cites W2013176211 @default.
- W3038108596 cites W2021134586 @default.
- W3038108596 cites W2038117078 @default.
- W3038108596 cites W2039298701 @default.
- W3038108596 cites W2060717956 @default.
- W3038108596 cites W2078399627 @default.
- W3038108596 cites W2079431112 @default.
- W3038108596 cites W2091586851 @default.
- W3038108596 cites W2103308780 @default.
- W3038108596 cites W2105137446 @default.
- W3038108596 cites W2107340950 @default.
- W3038108596 cites W2132921181 @default.
- W3038108596 cites W2166689829 @default.
- W3038108596 cites W2310476870 @default.
- W3038108596 cites W2340802388 @default.
- W3038108596 cites W2341969925 @default.
- W3038108596 cites W2462304292 @default.
- W3038108596 cites W2592766538 @default.
- W3038108596 cites W2604546177 @default.
- W3038108596 cites W2730292674 @default.
- W3038108596 cites W2741818978 @default.
- W3038108596 cites W2801201019 @default.
- W3038108596 cites W2884896273 @default.
- W3038108596 cites W2891492088 @default.
- W3038108596 cites W2969378985 @default.
- W3038108596 cites W4248364945 @default.
- W3038108596 cites W600932620 @default.
- W3038108596 doi "https://doi.org/10.1002/anie.202006438" @default.
- W3038108596 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7540565" @default.
- W3038108596 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32589318" @default.
- W3038108596 hasPublicationYear "2020" @default.
- W3038108596 type Work @default.
- W3038108596 sameAs 3038108596 @default.
- W3038108596 citedByCount "27" @default.
- W3038108596 countsByYear W30381085962020 @default.
- W3038108596 countsByYear W30381085962021 @default.
- W3038108596 countsByYear W30381085962022 @default.
- W3038108596 countsByYear W30381085962023 @default.
- W3038108596 crossrefType "journal-article" @default.
- W3038108596 hasAuthorship W3038108596A5001382768 @default.
- W3038108596 hasAuthorship W3038108596A5044900607 @default.
- W3038108596 hasAuthorship W3038108596A5081651773 @default.
- W3038108596 hasBestOaLocation W30381085961 @default.
- W3038108596 hasConcept C115624301 @default.
- W3038108596 hasConcept C145148216 @default.
- W3038108596 hasConcept C150394285 @default.
- W3038108596 hasConcept C178790620 @default.
- W3038108596 hasConcept C179303850 @default.
- W3038108596 hasConcept C179366358 @default.
- W3038108596 hasConcept C185592680 @default.
- W3038108596 hasConcept C192562407 @default.
- W3038108596 hasConcept C2778849931 @default.
- W3038108596 hasConcept C2779336533 @default.
- W3038108596 hasConcept C32909587 @default.
- W3038108596 hasConcept C34814092 @default.
- W3038108596 hasConcept C59822182 @default.
- W3038108596 hasConcept C71240020 @default.
- W3038108596 hasConcept C8010536 @default.
- W3038108596 hasConcept C86803240 @default.
- W3038108596 hasConceptScore W3038108596C115624301 @default.
- W3038108596 hasConceptScore W3038108596C145148216 @default.
- W3038108596 hasConceptScore W3038108596C150394285 @default.
- W3038108596 hasConceptScore W3038108596C178790620 @default.
- W3038108596 hasConceptScore W3038108596C179303850 @default.
- W3038108596 hasConceptScore W3038108596C179366358 @default.
- W3038108596 hasConceptScore W3038108596C185592680 @default.
- W3038108596 hasConceptScore W3038108596C192562407 @default.
- W3038108596 hasConceptScore W3038108596C2778849931 @default.
- W3038108596 hasConceptScore W3038108596C2779336533 @default.
- W3038108596 hasConceptScore W3038108596C32909587 @default.
- W3038108596 hasConceptScore W3038108596C34814092 @default.
- W3038108596 hasConceptScore W3038108596C59822182 @default.
- W3038108596 hasConceptScore W3038108596C71240020 @default.
- W3038108596 hasConceptScore W3038108596C8010536 @default.
- W3038108596 hasConceptScore W3038108596C86803240 @default.
- W3038108596 hasFunder F4320320847 @default.
- W3038108596 hasIssue "40" @default.
- W3038108596 hasLocation W30381085961 @default.