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- W3038848182 abstract "Abstract Near infrared (NIR)‐emissive polymers are attractive luminescent materials due to their utilities in biological, optoelectronic, and telecommunication applications. Herein we report the use of a dialkylamine‐strapped dithienylpyrrole (DTP) as an excited‐state intramolecular proton transfer (ESIPT) building block for producing NIR‐emissive π‐conjugated polymers. The study of a series of model compounds showed that the extension of π‐conjugation with a moderately electron‐accepting comonomer unit, dithientyl‐substituted thiazolo[5,4‐d]thiazole (TzTz), effectively stabilizes the zwitterionic ESIPT state while increasing the oscillator strength for the electronic transition from the ESIPT state. Consequently, a polymer consisted of DTP and TzTz units exhibited a significantly red‐shifted emission, exceeding 750 nm, from the ESIPT state in polar solvents." @default.
- W3038848182 created "2020-07-10" @default.
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- W3038848182 date "2020-07-23" @default.
- W3038848182 modified "2023-10-10" @default.
- W3038848182 title "A Near‐Infrared Emissive π‐Conjugated Polymer Consisting of an Excited‐State Intramolecular Proton Transfer Unit" @default.
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- W3038848182 doi "https://doi.org/10.1002/ajoc.202000234" @default.
- W3038848182 hasPublicationYear "2020" @default.
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