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• W3038889998 endingPage "127500" @default.
• W3038889998 startingPage "127500" @default.
• W3038889998 abstract "Lithium (Li+) is used in various applications involving pharmaceuticals, textile dyes, and batteries. Therefore, the demand for environmentally friendly and effective materials for Li+ uptake and recovery continues to increase. Herein, rice husk (RH) and coconut shell (CS) biomasses were used to fabricate honeycomb-networked biochar (BC) precursors via slow pyrolysis. RHBC- and CSBC-based MnO2 composites were synthesized by depositing MnO2 in various ratios onto RHBC and CSBC by varying the KMnO4 concentration (2%, 3%, and 4%), followed by simple ultrasonication and heat-treatment methodologies. The structural and physicochemical properties of all of the fabricated composites were analyzed using several different instrumental methods. The batch adsorption experiments were performed for comparative Li+-adsorption studies of RHBC-Mnx and CSBC-Mnx composites by optimizing several parameters (pH, adsorbent dose, Li+ initial concentration, and contact time). The comparative adsorption analysis revealed that the RHBC-Mnx composites exhibited stronger Li+-adsorption ability than the CSBC-Mnx composites and that increasing the MnO2 deposition to 3% in both cases led to maximum Li+ adsorption capacities (62.85 mg g−1 and 57.8 mg g−1), respectively. The kinetic studies show that Li+ adsorption proceeds through the pseudo-second-order mechanism. Li+ recovery was successfully carried out using HCl (eluting agent), thereby demonstrating the benefits of synthesized composites at the industrial scale. The current work indicates that the fabricated RHBC-Mnx and CSBC-Mnx composites may have potential for use as economical composites in eco-friendly applications such as Li+ adsorption and recovery from aqueous media." @default.
• W3038889998 created "2020-07-10" @default.
• W3038889998 creator A5016582981 @default.
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• W3038889998 date "2020-12-01" @default.
• W3038889998 modified "2023-10-05" @default.
• W3038889998 title "MnO2-decorated biochar composites of coconut shell and rice husk: An efficient lithium ions adsorption-desorption performance in aqueous media" @default.
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• W3038889998 doi "https://doi.org/10.1016/j.chemosphere.2020.127500" @default.
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• W3038889998 hasPublicationYear "2020" @default.
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