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- W3038992051 abstract "Regioselective difunctionalization of 2,6-difluorophenols with aryl sulfoxides and nucleophiles has been accomplished. The reaction is composed of (1) Pummerer-based [3,3] sigmatropic dearomatization to generate 2,4-cyclohexadienone, (2) Michael addition of a nucleophile, and (3) liberation of HF for rearomatization. Besides the [3,3] rearrangement, [2,3] sigmatropic rearrangement from sulfonium ylide generated from alkyl sulfoxide promotes the dearomatization, resulting in installation of α-sulfanylalkyl group." @default.
- W3038992051 created "2020-07-10" @default.
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- W3038992051 date "2020-07-07" @default.
- W3038992051 modified "2023-10-18" @default.
- W3038992051 title "Regioselective Difunctionalization of 2,6-Difluorophenols Triggered by Sigmatropic Dearomatization" @default.
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- W3038992051 doi "https://doi.org/10.1021/acs.orglett.0c01904" @default.
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