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- W3039069116 abstract "Phase relations in the ternary system MgO-Al2O3-Cr2O3 were determined at 1700 ± 15°C to delineate the stability field of spinel crystalline solutions. It was found that there is no solubility of Cr2O3 in MgCr2O4 spinel, and this is attributed to the high octahedral field stabilization energy for Cr3+ ion. By heating mixtures consisting of MgO and 50–66 mole% Cr2O8 in a reducing atmosphere at 1800–2000°C a new spinel-type crystalline solution was obtained having the general formulaData are presented concerning the synthesis, structure, electronic spectra and magnetic susceptibility of these crystalline solutions." @default.
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- W3039069116 date "1976-01-01" @default.
- W3039069116 modified "2023-10-17" @default.
- W3039069116 title "Trivalent and divalent chromium ions in spinels" @default.
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