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- W3039110312 abstract "A novel narrow band-gap chlorinated non-fullerene pentacyclic small molecule acceptor based on benzotriazole with extended absorption edge to the near-infrared (NIR) region, named BZIC-4Cl, was designed and synthesized. Through introducing multi-fused benzotriazole and IC-2Cl, BZIC-4Cl could maintain a lower optical bandgap of 1.38 eV with broad and efficient absorption band from 500 to 950 nm due to increased π−π interactions by the covalently locking thiophene and benzotriazole units. There is a stronger intermolecular charge transfer (ICT) effects between the BZTP core and IC-2Cl end-group. The purity and chemical structure of the acceptor, namely BZIC-4Cl, were tested by 1H NMR. Even though BZIC-4Cl showed slightly poor solubility in certain organic solvents, BZIC-4Cl showed broad and strong absorption with a narrow band-gap which can be matched with polymer donor for efficient organic solar cells." @default.
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- W3039110312 date "2020-07-01" @default.
- W3039110312 modified "2023-09-24" @default.
- W3039110312 title "Design, Synthesis and Photophysical Properties of Chlorinated Small Molecule Non-fullerene Acceptor Based on Benzotriazole for Organic Solar Cells" @default.
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- W3039110312 doi "https://doi.org/10.1088/1755-1315/508/1/012144" @default.
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