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- W3039206642 abstract "Infrared spectra of the CO2-N2 dimer are observed in the carbon dioxide nu3 asymmetric stretch region (~2350 cm-1) using a tunable infrared optical parametric oscillator to probe a pulsed slit jet supersonic expansion. Previous results for the b-type fundamental band are extended to higher values of Ka. An a-type combination band involving the lowest in-plane intermolecular bending mode is observed. This yields a value of 21.4 cm-1, and represents the first experimental determination of an intermolecular mode for CO2-N2. This intermolecular frequency is at odds with the value of 45.9 cm-1 obtained from a recent 4D intermolecular potential energy surface. In addition, two weak bands near 2337 cm-1 are assigned to the CO2 hot band transition (v1, v2, l2, v3) = (0111) <-- (0110). They yield a value of 2.307 cm-1 for the splitting of the degenerate CO2 nu2 bend into in-plane and out-of-plane components due to the presence of the nearby N2. The in-plane mode lies at lower energy relative to the out-of-plane mode." @default.
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- W3039206642 date "2020-07-07" @default.
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- W3039206642 title "Spectra of CO<sub>2</sub>–N<sub>2</sub> dimer in the 4.2 μm region: Symmetry breaking of the intramolecular CO<sub>2</sub> bend, the intermolecular bend, and higher <i>K</i>-values for the fundamental" @default.
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- W3039206642 doi "https://doi.org/10.1063/5.0012531" @default.
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