FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3039453320> ?p ?o ?g. }

• W3039453320 endingPage "715" @default.
• W3039453320 startingPage "715" @default.
• W3039453320 abstract "The gas-phase reaction between trans-2-methyl-2-butenal and chlorine (Cl) atoms has been studied in a simulation chamber at 298 ± 2 K and 760 ± 5 Torr of air under free-NOx conditions. The rate coefficient of this reaction was determined as k = (2.45 ± 0.32) × 10−10 cm3 molecule−1 s−1 by using a relative method and Fourier transform infrared spectroscopy. In addition to this technique, gas chromatography coupled to mass spectrometry and proton transfer time-of-flight mass spectrometry were used to detect and monitor the time evolution of the gas-phase reaction products. The major primary reaction product from the addition of Cl to the C-3 of trans-2-methyl-2-butenal was 3-chloro-2-butanone, with a molar yield (YProd) of (52.5 ± 7.3)%. Acetaldehyde (Y = (40.8 ± 0.6)%) and HCl were also identified, indicating that the H-abstraction by Cl from the aldehyde group is a reaction pathway as well. Secondary organic aerosol (SOA) formation was investigated by using a fast mobility particle sizer spectrometer. The SOA yield in the Cl + trans-2-methyl-2-butenal reaction is reported to be lower than 2.4%, thus its impact can be considered negligible. The atmospheric importance of the titled reaction is similar to the corresponding OH reaction in areas with high Cl concentration." @default.
• W3039453320 created "2020-07-10" @default.
• W3039453320 creator A5030345848 @default.
• W3039453320 creator A5051831842 @default.
• W3039453320 creator A5070389361 @default.
• W3039453320 creator A5074288980 @default.
• W3039453320 date "2020-07-05" @default.
• W3039453320 modified "2023-09-25" @default.
• W3039453320 title "Gas-Phase Reaction of trans-2-Methyl-2-butenal with Cl: Kinetics, Gaseous Products, and SOA Formation" @default.
• W3039453320 cites W1593655292 @default.
• W3039453320 cites W1666891192 @default.
• W3039453320 cites W1980124845 @default.
• W3039453320 cites W1984457243 @default.
• W3039453320 cites W1986657402 @default.
• W3039453320 cites W1986964795 @default.
• W3039453320 cites W1994183825 @default.
• W3039453320 cites W1994831894 @default.
• W3039453320 cites W1995193615 @default.
• W3039453320 cites W1998792983 @default.
• W3039453320 cites W2009845646 @default.
• W3039453320 cites W2023037439 @default.
• W3039453320 cites W2029337195 @default.
• W3039453320 cites W2035014908 @default.
• W3039453320 cites W2039459945 @default.
• W3039453320 cites W2041032898 @default.
• W3039453320 cites W2041904070 @default.
• W3039453320 cites W2044724516 @default.
• W3039453320 cites W2067157510 @default.
• W3039453320 cites W2067342499 @default.
• W3039453320 cites W2080798809 @default.
• W3039453320 cites W2083227835 @default.
• W3039453320 cites W2083988594 @default.
• W3039453320 cites W2089584265 @default.
• W3039453320 cites W2090475777 @default.
• W3039453320 cites W2102144400 @default.
• W3039453320 cites W2116372664 @default.
• W3039453320 cites W2127297900 @default.
• W3039453320 cites W2131868501 @default.
• W3039453320 cites W2135497701 @default.
• W3039453320 cites W2330799264 @default.
• W3039453320 cites W2531159588 @default.
• W3039453320 cites W264113838 @default.
• W3039453320 cites W2767683865 @default.
• W3039453320 cites W2979314390 @default.
• W3039453320 doi "https://doi.org/10.3390/atmos11070715" @default.
• W3039453320 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7116312" @default.
• W3039453320 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33154821" @default.
• W3039453320 hasPublicationYear "2020" @default.
• W3039453320 type Work @default.
• W3039453320 sameAs 3039453320 @default.
• W3039453320 citedByCount "3" @default.
• W3039453320 countsByYear W30394533202021 @default.
• W3039453320 countsByYear W30394533202022 @default.
• W3039453320 crossrefType "journal-article" @default.
• W3039453320 hasAuthorship W3039453320A5030345848 @default.
• W3039453320 hasAuthorship W3039453320A5051831842 @default.
• W3039453320 hasAuthorship W3039453320A5070389361 @default.
• W3039453320 hasAuthorship W3039453320A5074288980 @default.
• W3039453320 hasBestOaLocation W30394533201 @default.
• W3039453320 hasConcept C113196181 @default.
• W3039453320 hasConcept C121332964 @default.
• W3039453320 hasConcept C134121241 @default.
• W3039453320 hasConcept C139066938 @default.
• W3039453320 hasConcept C148898269 @default.
• W3039453320 hasConcept C161790260 @default.
• W3039453320 hasConcept C162356407 @default.
• W3039453320 hasConcept C175113610 @default.
• W3039453320 hasConcept C178790620 @default.
• W3039453320 hasConcept C185592680 @default.
• W3039453320 hasConcept C191897082 @default.
• W3039453320 hasConcept C192562407 @default.
• W3039453320 hasConcept C2777595113 @default.
• W3039453320 hasConcept C2778565081 @default.
• W3039453320 hasConcept C2779825165 @default.
• W3039453320 hasConcept C2780161600 @default.
• W3039453320 hasConcept C2780263894 @default.
• W3039453320 hasConcept C36663273 @default.
• W3039453320 hasConcept C43617362 @default.
• W3039453320 hasConcept C62520636 @default.
• W3039453320 hasConceptScore W3039453320C113196181 @default.
• W3039453320 hasConceptScore W3039453320C121332964 @default.
• W3039453320 hasConceptScore W3039453320C134121241 @default.
• W3039453320 hasConceptScore W3039453320C139066938 @default.
• W3039453320 hasConceptScore W3039453320C148898269 @default.
• W3039453320 hasConceptScore W3039453320C161790260 @default.
• W3039453320 hasConceptScore W3039453320C162356407 @default.
• W3039453320 hasConceptScore W3039453320C175113610 @default.
• W3039453320 hasConceptScore W3039453320C178790620 @default.
• W3039453320 hasConceptScore W3039453320C185592680 @default.
• W3039453320 hasConceptScore W3039453320C191897082 @default.
• W3039453320 hasConceptScore W3039453320C192562407 @default.
• W3039453320 hasConceptScore W3039453320C2777595113 @default.
• W3039453320 hasConceptScore W3039453320C2778565081 @default.
• W3039453320 hasConceptScore W3039453320C2779825165 @default.
• W3039453320 hasConceptScore W3039453320C2780161600 @default.
• W3039453320 hasConceptScore W3039453320C2780263894 @default.
• W3039453320 hasConceptScore W3039453320C36663273 @default.
• W3039453320 hasConceptScore W3039453320C43617362 @default.

• next