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- W3039522137 abstract "Conjugated microporous polymer (CMP)-based energy-storage materials were developed for pseudocapacitors. Nanoparticulate CMP (N-CMP) with an average diameter of 41±4 nm was prepared through kinetic growth control in the Sonogashira coupling of 1,3,5-triethynylbenzene with 1,4-diiodobenzene. The N-CMP is rich in a diphenylacetylene moiety in its chemical structure. Through the FeCl3 -catalyzed oxidation of diphenylacetylene moieties, N-CMP with benzil moieties (N-CMP-BZ) was prepared and showed enhanced electrochemical performance as an electrode material of pseudocapacitors, compared with CMP, CMP-BZ, and N-CMP. In model studies, the benzil was redox active and showed two-electron reduction behavior. The excellent electrochemical performance of N-CMP-BZ is attributable to the enhanced utilization of functional sites by a nanosize effect and the additional redox contribution of benzil moieties." @default.
- W3039522137 created "2020-07-10" @default.
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- W3039522137 date "2020-09-07" @default.
- W3039522137 modified "2023-10-16" @default.
- W3039522137 title "Nanoparticulate Conjugated Microporous Polymer with Post‐Modified Benzils for Enhanced Pseudocapacitor Performance" @default.
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- W3039522137 doi "https://doi.org/10.1002/chem.202002311" @default.
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