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• W3039580582 abstract "The Boekelheide rearrangement is often employed for the oxy-functionalization of alkyl groups in the 2-position of pyridines, yet the corresponding alkylation reaction has so far not been realized since 1954. N-Alkenoxypyridinium functionalization has been widely applied to synthesize various carbonyl compounds by only using the carbonyl unit. Herein, we describe a simple yet efficient alkylation of N-alkenoxypyridiniums through the Boekelheide reaction for the synthesis of β-2-pyridyl alkyl ketones." @default.
• W3039580582 created "2020-07-10" @default.
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• W3039580582 date "2020-07-07" @default.
• W3039580582 modified "2023-09-24" @default.
• W3039580582 title "Site-Selective Pyridyl Alkyl Ketone Synthesis from <i>N</i>-Alkenoxypyridiniums through Boekelheide-Type Rearrangements" @default.
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• W3039580582 doi "https://doi.org/10.1021/acs.orglett.0c01984" @default.
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