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- W3039589957 abstract "The one-pot multistep ethyltellurenylation reaction of epoxides with elemental tellurium and lithium triethylborohydride is described. The reaction mechanism was experimentally investigated. Dilithium ditelluride and triethyl borane, formed from elemental tellurium and lithium triethylborohydride, were shown to be the key species involved in the reaction mechanism. Epoxides undergo ring-opening reaction with dilithium ditelluride to afford β-hydroxy ditellurides, which are sequentially converted into the corresponding β-hydroxy-alkyl ethyl tellurides by transmetalation with triethyl borane, reasonably proceeding through the SH2 mechanism." @default.
- W3039589957 created "2020-07-10" @default.
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- W3039589957 date "2020-07-06" @default.
- W3039589957 modified "2023-09-26" @default.
- W3039589957 title "Unexpected Ethyltellurenylation of Epoxides with Elemental Tellurium under Lithium Triethylborohydride Conditions" @default.
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- W3039589957 doi "https://doi.org/10.3390/chemistry2030041" @default.
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