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- W3040201908 abstract "Cathodes of rechargeable Zn batteries typically face the issues of irreversible phase transformation, structure collapse, and volume expansion during repeated charge/discharge cycles, which result in an increased transfer resistance and poor long-term cycling stability. Herein, a facile F doping strategy is developed to boost the cycling stability of nickel cobalt carbonate hydroxide (NiCo-CH) cathode. Benefiting from the extremely high electronegativity, the phase and morphology stabilities as well as the electrical conductivity of NiCo-CH are remarkably enhanced by F incorporation (NiCo-CH-F). Phase interface and amorphous microdomains are also introduced, which are favorable for the electrochemical performance of cathode. Benefiting from these features, NiCo-CH-F delivers a high capacity (245 mA h g-1 ), excellent rate capability (64% retention at 8 A g-1 ), and outstanding cycling stability (maintains 90% after 10 000 cycles). Moreover, the quasi-solid-state battery also manifests superior cycling stability (maintains 90% after 7200 cycles) and desirable flexibility. This work offers a general strategy to boost the cycling stability of cathode materials for aqueous Zn batteries." @default.
- W3040201908 created "2020-07-10" @default.
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- W3040201908 date "2020-06-30" @default.
- W3040201908 modified "2023-10-16" @default.
- W3040201908 title "Boosting the Cycling Stability of Aqueous Flexible Zn Batteries via F Doping in Nickel–Cobalt Carbonate Hydroxide Cathode" @default.
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- W3040201908 doi "https://doi.org/10.1002/smll.202001935" @default.
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