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- W3040375573 abstract "• New heterogeneous catalyst comprising nano-porous MCM-48 & 12-tungstosilicic acid. • Solvent-free acetalization of glycerol with benzaldehyde & furfural at ambient reaction conditions. • Synthesis of dioxane derivatives with > 85 % conversion and > 60 % selectivity with high TON. The present article demonstrates designing of novel catalyst, 12-tungstosilicic acid (TSA) anchored to ordered nano-porous MCM-48 (nMCM-48); TSA/nMCM-48, characterization and evaluation for synthesis of bio-fuel additives via glycerol valorisation with aromatic aldehydes. The nanopores of support were confirmed by BET and TEM while the interaction between TSA and nMCM-48 was confirmed by decrease in the surface area and pore volume of the catalysts. Assessment of vital reaction parameters (% loading of active species, mole ratio of reactants, catalyst amount, temperature and time) were performed to achieve maximum conversion of glycerol. The catalyst showed noteworthy performance at 30 °C towards conversion (>85 %) and thermodynamically stable dioxane derivative (>60 %) with remarkable TON (5945 for benzaldehyde and 7355 for furfural). The catalyst was regenerated and used for successive four catalytic runs with almost same activity. The superiority of novel catalyst is because of its geometry and nano porosity." @default.
- W3040375573 created "2020-07-10" @default.
- W3040375573 creator A5006588212 @default.
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- W3040375573 date "2020-07-01" @default.
- W3040375573 modified "2023-10-17" @default.
- W3040375573 title "Low temperature synthesis of bio-fuel additives via valorisation of glycerol with benzaldehyde as well as furfural over a novel sustainable catalyst, 12-tungstosilicic acid anchored to ordered cubic nano-porous MCM-48" @default.
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- W3040375573 doi "https://doi.org/10.1016/j.apcata.2020.117729" @default.
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