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- W3040765703 abstract "Gold nanoparticles have been used for centuries, both for decoration and in medical applications. More recently, many of the major advances in cluster chemistry have involved well-defined clusters containing tens or hundreds of atoms, either with or without a ligand shell. In this paper we report the synthesis of two gold/lead clusters, [Au8Pb33]6- and [Au12Pb44]8-, both of which contain nido [Au@Pb11]3- icosahedra surrounding a core of Au atoms. Analogues of these large clusters are not found in the corresponding Ag chemistry: instead, the Ag-centered nido icosahedron, [Ag@Pb11]3-, is the only isolated product. The structural chemistry, along with the mass spectrometry which shows the existence of [Au2Pb11]2- but not [Ag2Pb11]2-, leads us to propose that the former species is the key intermediate in the growth of the larger clusters. Density functional theory indicates that secondary π-type interactions between the [Au@Pb11]3- ligands and the gold core play a significant part in stabilizing the larger clusters." @default.
- W3040765703 created "2020-07-16" @default.
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- W3040765703 date "2020-07-10" @default.
- W3040765703 modified "2023-10-11" @default.
- W3040765703 title "A family of lead clusters with precious metal cores" @default.
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- W3040765703 doi "https://doi.org/10.1038/s41467-020-17187-4" @default.
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