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- W3040789030 abstract "Seven new (1–7) and 11 known diterpenoids were isolated and identified from Caryopteris aureoglandulosa. These diterpenoids were structurally determined by HRESIMS and NMR spectroscopic analyses, single-crystal X-ray diffraction, and ECD data. Structurally, aureoglandulosin A (1) is a highly oxygenated abietane diterpenoid with an unprecedented 7/6/6/5-ring system. Aureoglandulosins B (2) and C (3) represent naturally occurring new diterpenoids with an unusual 6/6/6/5-ring system. Additionally, the configurations of two known abietane diterpenoids 11 and 12 were determined by X-ray crystallographic data analysis for the first time. A plausible biosynthetic pathway for compounds 1–3 is proposed. The cytotoxicity of all isolates was evaluated, and compounds 1 and 11 exhibited significant cytotoxic activity against some cell lines with IC50 values in the range 1.6–8.2 μM." @default.
- W3040789030 created "2020-07-16" @default.
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- W3040789030 date "2020-07-13" @default.
- W3040789030 modified "2023-10-17" @default.
- W3040789030 title "Cytotoxic Diterpenoids from <i>Caryopteris aureoglandulosa</i>" @default.
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- W3040789030 doi "https://doi.org/10.1021/acs.jnatprod.9b01052" @default.
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