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- W3040967564 abstract "The C−H bond activation of the Jahn–Teller distorted adamantane cation by a single H2O molecule is probed by IR spectroscopy and DFT calculations in the Research Article by O. Dopfer and co-workers on page 12098. The results provide a quantitative molecular-level understanding of the initial activation by a single polar solvent molecule in the radical cation mechanism for the functionalization of diamondoids. A drastic C−H stretch frequency shift along with quasi-free internal rotation of the H2O ligand is observed." @default.
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- W3040967564 date "2020-06-22" @default.
- W3040967564 modified "2023-10-03" @default.
- W3040967564 title "Back Cover: Infrared Spectrum of the Adamantane + –Water Cation: Hydration‐Induced C−H Bond Activation and Free Internal Water Rotation (Angew. Chem. Int. Ed. 29/2020)" @default.
- W3040967564 doi "https://doi.org/10.1002/anie.202007850" @default.
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