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- W3041472289 abstract "X‐ray total scattering is applied to a series of molecular liquids including the CsF salt, which is expected to be a promising electrolyte in fluoride shuttle batteries. These electrolytes are composed of solvent molecules and addition agents (AAs), together with CsF. Tetraglyme (G4) or γ‐butyrolactone (GBL) is used as a solvent molecule, and lithium bis(fluorosulfonyl)imide (LiFSI), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), triphenylboroxine (TPhBX), or lithium bis(oxaloto)borate (LiBOB) as an AA. It is found that an additional peak appears on the low‐ Q side of the main peak by the addition of LiFSI, LiTFSI, or TPhBX to the solvent, which indicates that correlation between cation and anion molecules is induced by these AAs. Furthermore, the position and the intensity of this peak are changed by the addition of the CsF salt, suggesting the modification of the correlation in the presence of the Cs + and F − ions." @default.
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- W3041472289 date "2020-07-21" @default.
- W3041472289 modified "2023-09-26" @default.
- W3041472289 title "X‐Ray Total Scattering of Electrolytes in Liquid‐Based Fluoride Shuttle Battery: Electrolyte Composition Dependence of the Low‐ <i>Q</i> Peak" @default.
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- W3041472289 doi "https://doi.org/10.1002/pssb.202000202" @default.
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