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- W3041809184 abstract "Abstract A new family of phosphine‐ligated dicyanoarylgold(III) complexes has been prepared and their reactivity towards reductive elimination has been studied in detail. Both, a highly positive entropy of activation and a primary 12/13 C KIE suggest a late concerted transition state while Hammett analysis and DFT calculations indicate that the process is asynchronous. As a result, a distinct mechanism involving an asynchronous concerted reductive elimination for the overall C(sp 2 )−C(sp)N bond forming reaction is characterized herein, for the first time, complementing previous studies reported for C(sp 3 )−C(sp 3 ), C(sp 2 )−C(sp 2 ), and C(sp 3 )−C(sp 2 ) bond formation processes taking place on gold(III) species." @default.
- W3041809184 created "2020-07-16" @default.
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- W3041809184 date "2020-08-13" @default.
- W3041809184 modified "2023-10-01" @default.
- W3041809184 title "Mechanistic Insights into C(sp<sup>2</sup>)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes" @default.
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- W3041809184 doi "https://doi.org/10.1002/anie.202005731" @default.
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