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- W3042286475 endingPage "10181" @default.
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- W3042286475 abstract "The stereoselective oxidative rearrangement of disubstituted unactivated olefins has been achieved using a hypervalent iodine(III) reagent. The aryl group undergoes 1,2-migration to give tert-α-arylated aldehydes (as acetals). The preparation of these aldehydes/acetals, especially containing a tert-benzylic stereocenter, has remained challenging. This migration-based method provides a complementary approach over the known α-substitution-based methods for accessing this class of molecules." @default.
- W3042286475 created "2020-07-23" @default.
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- W3042286475 date "2020-07-14" @default.
- W3042286475 modified "2023-10-16" @default.
- W3042286475 title "Stereoselective Oxidative Rearrangement of Disubstituted Unactivated Alkenes Using Hypervalent Iodine(III) Reagent" @default.
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- W3042286475 doi "https://doi.org/10.1021/acs.joc.0c00347" @default.
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