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• W3042603205 abstract "Highly enantioselective organocatalytic construction of spirochromans containing a tetrasubstituted stereocenter was developed. Intramolecular oxy-Michael addition was catalyzed with a bifunctional cinchona alkaloid thiourea catalyst. A variety of spirochroman compounds containing a tetrasubstituted stereocenter were obtained with excellent enantioselectivities of up to 99% enantiomeric excess. The reaction was applied to the asymmetric formal synthesis of (−)-(R)-cordiachromene." @default.
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• W3042603205 date "2020-07-16" @default.
• W3042603205 modified "2023-09-26" @default.
• W3042603205 title "Enantioselective Organocatalytic Construction of Spirochroman Derivatives" @default.
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• W3042603205 doi "https://doi.org/10.1021/acs.joc.0c00589" @default.
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