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- W3043020107 abstract "Abstract This study presents the thermodynamic properties and phase equilibrium of Pb-Pd system determined both experimentally and theoretically. The integral mixing enthalpy of the Pb-Pd liquid solutions was found to be negative in the entire measured concentration range at 828, 929, 1005, 1026 and 1085 K similar as the activity deviation of Pb presented in the literature. A good correlation between the experimentally obtained results of mixing enthalpy and the available literature data was found. Moreover, a new thermodynamic description of the Pb-Pd system was proposed with the use of Calphad and Ab-initio methods based on the all available in the literature and determined in this study experimental data. Thermodynamic properties and phase diagram data calculated with the use of the optimised thermodynamic parameters elaborated in this work are consistent with the experimental and predicted results." @default.
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- W3043020107 date "2020-10-01" @default.
- W3043020107 modified "2023-09-23" @default.
- W3043020107 title "On the Pb-Pd system. Calorimetric studies and ab-initio aided thermodynamic calculations" @default.
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- W3043020107 doi "https://doi.org/10.1016/j.molliq.2020.113806" @default.
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