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- W3043079404 abstract "Abstract Chromium complexes have found very little applications as hydrogenation catalysts. Here, we report a Cr‐catalyzed semi‐hydrogenation of internal alkynes to the corresponding Z ‐alkenes with good stereocontrol (up to 99/1 for dialkyl alkynes). The catalyst comprises the commercial reagents chromium(III) acetylacetonate, Cr(acac) 3 , and diisobutylaluminium hydride, DIBAL−H, in THF. The semi‐hydrogenation operates at mild conditions (1‐5 bar H 2 , 30 °C)." @default.
- W3043079404 created "2020-07-23" @default.
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- W3043079404 date "2020-09-01" @default.
- W3043079404 modified "2023-10-09" @default.
- W3043079404 title "Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes" @default.
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- W3043079404 doi "https://doi.org/10.1002/cctc.202000994" @default.
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