Matches in SemOpenAlex for { <https://semopenalex.org/work/W3043291256> ?p ?o ?g. }
- W3043291256 endingPage "10503" @default.
- W3043291256 startingPage "10488" @default.
- W3043291256 abstract "Highly efficient, selective, and direct C–H peroxidation of 9-substituted fluorenes has been achieved using a Mn–2,2′-bipyridine catalyst via radical–radical cross-coupling. Moreover, this method effectively promotes the vicinal bisperoxidation of sterically hindered various substituted arylidene-9H-fluorene/arylideneindolin-2-one derivatives to afford highly substituted bisperoxides with high selectivity over the oxidative cleavage of C═C bond that usually forms the ketone of an aldehyde. Furthermore, a new approach for the synthesis of (Z)-6-benzylidene-6H-benzo[c]chromene has been achieved via an acid-catalyzed skeletal rearrangement of these peroxides. For the first time, unlike O–O bond cleavage, reductive C–O bond cleavage in peroxides using the Pd catalyst and H2 is described, which enables the reversible reaction to afford exclusively deperoxidized products. A detailed mechanism for peroxidation, molecular rearrangement, and deperoxidation has been proposed with preliminary experimental evidences." @default.
- W3043291256 created "2020-07-23" @default.
- W3043291256 creator A5025268103 @default.
- W3043291256 creator A5060246769 @default.
- W3043291256 creator A5084407502 @default.
- W3043291256 creator A5084477750 @default.
- W3043291256 date "2020-07-17" @default.
- W3043291256 modified "2023-10-06" @default.
- W3043291256 title "Manganese-Catalyzed Synthesis of Quaternary Peroxides: Application in Catalytic Deperoxidation and Rearrangement Reactions" @default.
- W3043291256 cites W1964587561 @default.
- W3043291256 cites W1985229433 @default.
- W3043291256 cites W1985767904 @default.
- W3043291256 cites W1994787003 @default.
- W3043291256 cites W1996758192 @default.
- W3043291256 cites W1997958867 @default.
- W3043291256 cites W2016650888 @default.
- W3043291256 cites W2023056883 @default.
- W3043291256 cites W2023264490 @default.
- W3043291256 cites W2024560011 @default.
- W3043291256 cites W2037820199 @default.
- W3043291256 cites W2043525015 @default.
- W3043291256 cites W2044210032 @default.
- W3043291256 cites W2053887946 @default.
- W3043291256 cites W2070854679 @default.
- W3043291256 cites W2076583866 @default.
- W3043291256 cites W2079729488 @default.
- W3043291256 cites W2108402502 @default.
- W3043291256 cites W2108976747 @default.
- W3043291256 cites W2140813060 @default.
- W3043291256 cites W2163238869 @default.
- W3043291256 cites W2197933241 @default.
- W3043291256 cites W2207376786 @default.
- W3043291256 cites W2258749495 @default.
- W3043291256 cites W2316209249 @default.
- W3043291256 cites W2316354259 @default.
- W3043291256 cites W2323219058 @default.
- W3043291256 cites W2325230458 @default.
- W3043291256 cites W2331554660 @default.
- W3043291256 cites W2412429925 @default.
- W3043291256 cites W2477606128 @default.
- W3043291256 cites W2494367468 @default.
- W3043291256 cites W2557182587 @default.
- W3043291256 cites W2588437643 @default.
- W3043291256 cites W272936314 @default.
- W3043291256 cites W2777222149 @default.
- W3043291256 cites W2791527718 @default.
- W3043291256 cites W2885995712 @default.
- W3043291256 cites W2915315750 @default.
- W3043291256 cites W2916327891 @default.
- W3043291256 cites W2999322975 @default.
- W3043291256 cites W3024412997 @default.
- W3043291256 doi "https://doi.org/10.1021/acs.joc.0c00837" @default.
- W3043291256 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32678600" @default.
- W3043291256 hasPublicationYear "2020" @default.
- W3043291256 type Work @default.
- W3043291256 sameAs 3043291256 @default.
- W3043291256 citedByCount "9" @default.
- W3043291256 countsByYear W30432912562021 @default.
- W3043291256 countsByYear W30432912562022 @default.
- W3043291256 countsByYear W30432912562023 @default.
- W3043291256 crossrefType "journal-article" @default.
- W3043291256 hasAuthorship W3043291256A5025268103 @default.
- W3043291256 hasAuthorship W3043291256A5060246769 @default.
- W3043291256 hasAuthorship W3043291256A5084407502 @default.
- W3043291256 hasAuthorship W3043291256A5084477750 @default.
- W3043291256 hasConcept C118792377 @default.
- W3043291256 hasConcept C127413603 @default.
- W3043291256 hasConcept C155647269 @default.
- W3043291256 hasConcept C161790260 @default.
- W3043291256 hasConcept C175156509 @default.
- W3043291256 hasConcept C178790620 @default.
- W3043291256 hasConcept C185592680 @default.
- W3043291256 hasConcept C187320778 @default.
- W3043291256 hasConcept C201194858 @default.
- W3043291256 hasConcept C2777738585 @default.
- W3043291256 hasConcept C2779825165 @default.
- W3043291256 hasConcept C3044715 @default.
- W3043291256 hasConcept C43369102 @default.
- W3043291256 hasConcept C71240020 @default.
- W3043291256 hasConcept C75473681 @default.
- W3043291256 hasConceptScore W3043291256C118792377 @default.
- W3043291256 hasConceptScore W3043291256C127413603 @default.
- W3043291256 hasConceptScore W3043291256C155647269 @default.
- W3043291256 hasConceptScore W3043291256C161790260 @default.
- W3043291256 hasConceptScore W3043291256C175156509 @default.
- W3043291256 hasConceptScore W3043291256C178790620 @default.
- W3043291256 hasConceptScore W3043291256C185592680 @default.
- W3043291256 hasConceptScore W3043291256C187320778 @default.
- W3043291256 hasConceptScore W3043291256C201194858 @default.
- W3043291256 hasConceptScore W3043291256C2777738585 @default.
- W3043291256 hasConceptScore W3043291256C2779825165 @default.
- W3043291256 hasConceptScore W3043291256C3044715 @default.
- W3043291256 hasConceptScore W3043291256C43369102 @default.
- W3043291256 hasConceptScore W3043291256C71240020 @default.
- W3043291256 hasConceptScore W3043291256C75473681 @default.
- W3043291256 hasFunder F4320320721 @default.
- W3043291256 hasFunder F4320320767 @default.
- W3043291256 hasFunder F4320324168 @default.