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- W3043306557 abstract "Caesium propanoate monohydrate, Cs + ·C 3 H 5 O 2 − ·H 2 O, is composed of two symmetry-independent Cs + cations, which are situated on the special position 4 e of space group P overline42 1 m , one symmetry-independent propanoate molecule in a general position and a pair of water molecules also situated on special position 4 e . Two pairs of these symmetry-independent cations, four propanoate molecules and two pairs of symmetry-independent water molecules form a repeat unit. These units form columns that are directed along the c axis and possess symmetry mm 2. There are four such columns passing through each unit cell. Each column is interconnected to its neighbours by four bifurcated three-centred O w —H...O p (w = water, p = propanoate) hydrogen bonds of moderate strength. There are also four intramolecular O w —H...O p hydrogen bonds of moderate strength within each column. One Cs + cation is coordinated by six oxygen atoms (two water and four carboxylate) in a trigonal–prismatic geometry, while the other Cs + cation is coordinated by four water and four carboxylate O atoms in a tetragonal–prismatic arrangement." @default.
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- W3043306557 date "2020-07-17" @default.
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- W3043306557 title "Caesium propanoate monohydrate" @default.
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- W3043306557 doi "https://doi.org/10.1107/s2056989020009639" @default.
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