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- W3043360879 abstract "A novel tetranuclear Gd(III)-based cluster, namely [Gd4(HL)4(CH3O)4] •3CH3OH (1), has been successfully synthesized by using a polydentate Schiff base ligand (H3L) reacted with Gd(acac)3•2H2O. The crystal structure and magnetic property of cluster 1 have been completely studied. Crystal structure study reveals that cluster 1 is a tetranuclear compound and the four center Gd(III) ions display a tetrahedral arrangement. The magnetic research suggests that cluster 1 shows cryogenic magnetic refrigeration property with a larger magnetic entropy (−ΔSm = 30.42 J K−1 kg−1, T = 2.0 K and ΔH = 7.0 T)." @default.
- W3043360879 created "2020-07-23" @default.
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- W3043360879 date "2020-12-01" @default.
- W3043360879 modified "2023-10-01" @default.
- W3043360879 title "A novel tetranuclear Gd(III)-based cluster showing larger magnetic refrigeration property" @default.
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- W3043360879 doi "https://doi.org/10.1016/j.molstruc.2020.128906" @default.
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