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- W3043406629 endingPage "5950" @default.
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- W3043406629 abstract "A stereoselective synthesis of the highly advanced intermediates towards the revised structure of palmerolide C and 10-epi-palmerolide C is described in this paper. The required key fragments C1-C6, C7-C14 and C15-C23 have been successfully assembled in a convergent manner to access the C1-C23 framework bearing all the five stereocenters present in the natural product. The synthesis involves the Julia-Kocienski reaction, Yamaguchi esterification, Takai olefination and regioselective epoxide opening as key steps. The proposed route is flexible and could also be applied to the synthesis of structurally related palmerolides." @default.
- W3043406629 created "2020-07-23" @default.
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- W3043406629 date "2020-01-01" @default.
- W3043406629 modified "2023-09-24" @default.
- W3043406629 title "Synthetic studies on palmerolide C: synthesis of an advanced intermediate towards the revised structure of palmerolide C" @default.
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- W3043406629 doi "https://doi.org/10.1039/d0ob01140a" @default.
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