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- W3043489905 abstract "Fast 1H magic-angle spinning (MAS) solid-state NMR spectroscopywas utilized for quantitative analysis of the linker composition andspatial arrangement of functional groups of MTV-UiO-66–(BDC–CH3)x–(BDC–OH)y–(BDC–NH2)1–x−y. 2D 1H–1H DQ–SQ MAS NMR experiments facilitate the 1H NMR chemical shift assignments. It was demonstrated that the fast 1H MAS technique could improve the resolution of 1H NMR spectra and allow the quantitative determination of the relativecontent of functional linkers without acid-digested treatment of MTV-UiO-66.The spatial proximities of various components including BDC–CH3 and BDC–OH were verified from the 2D 1H–1H spin diffusion homonuclear correlation experiments. Therelative intensities of the 1H–1H spin-diffusionbuildup curves via OH → CH3 and CH3 →OH pathways were closely related to the linker composition of MTV-UiO-66.Additionally, the extracted slices along with the CH3 siteand OH site from the 2D 1H–1H spin diffusionNMR spectra are nearly the same as the corresponding 1D 1H MAS NMR spectra, indicating that the three functional linkers arein approximately random distribution in MTV-UiO-66-A and MTV-UiO-66-B.This work provides an efficient approach to examine the spatial arrangementof MTV-MOFs containing three distinct linkers." @default.
- W3043489905 created "2020-07-23" @default.
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- W3043489905 date "2020-07-17" @default.
- W3043489905 modified "2023-10-11" @default.
- W3043489905 title "Quantitative Analysis of Linker Composition and Spatial Arrangement of Multivariate Metal–Organic Framework UiO-66 through <sup>1</sup>H Fast MAS NMR" @default.
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- W3043489905 doi "https://doi.org/10.1021/acs.jpcc.0c04244" @default.
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