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- W3043633500 endingPage "119339" @default.
- W3043633500 startingPage "119339" @default.
- W3043633500 abstract "• ‘Nanoplatelet-on-nanoarray’ electrocatalyst is obtained from MOF nanoarrays. • The Electrochem-assisted transformation greatly increases the surface active sites. • Synergy between Ni/Co and unique structure contribute to superior anodic activity. • The electrode shows universal robustness towards oxidation of organic molecules. • HMF and bio-glycerol are upgraded to value-added FDCA and formate with high FE. Replacing oxygen evolution reaction with thermodynamically more favorable organic oxidation reactions is considered as attractive approach to enhance the energy conversion efficiency in electrochemical water splitting. Herein, ‘Nanoplatelet-on-Nanoarray’ NiCo hydroxide-based electrocatalysts (t-NiCo-MOF) fabricated from the facile transformation of bimetallic metal-organic framework nanoarrays is reported to exhibit rich surface active sites and unprecedented activity towards the oxidation of organic molecules including 5-hydroxymethylfurfural, urea, methanol and glycerol. Benefitting from the synergy between Ni/Co and unique nanostructure which facilitates the charge and mass transfer, the optimal electrode exhibits current densities of 600∼730 mA/cm 2 at 1.4 V vs RHE and the Tafel slopes are in the range of 35∼58 mV/dec depending on the oxidized species. Value-added chemicals such as 2,5-furandicarboxylic acid and formate are produced from HMF and methanol/glycerol (main constituents of ‘bio-glycerol’) with high FE and superior stability, demonstrating its promises in high-throughput electrochemical biomass upgrading." @default.
- W3043633500 created "2020-07-23" @default.
- W3043633500 creator A5003974306 @default.
- W3043633500 creator A5009884211 @default.
- W3043633500 creator A5015800353 @default.
- W3043633500 creator A5033466951 @default.
- W3043633500 creator A5054688366 @default.
- W3043633500 creator A5073216396 @default.
- W3043633500 date "2020-12-01" @default.
- W3043633500 modified "2023-10-05" @default.
- W3043633500 title "Constructing multifunctional ‘Nanoplatelet-on-Nanoarray’ electrocatalyst with unprecedented activity towards novel selective organic oxidation reactions to boost hydrogen production" @default.
- W3043633500 cites W1597569575 @default.
- W3043633500 cites W1971113415 @default.
- W3043633500 cites W2005673486 @default.
- W3043633500 cites W2029110522 @default.
- W3043633500 cites W2040634925 @default.
- W3043633500 cites W2045305817 @default.
- W3043633500 cites W2060033270 @default.
- W3043633500 cites W2070491781 @default.
- W3043633500 cites W2090224664 @default.
- W3043633500 cites W2098547240 @default.
- W3043633500 cites W2101799653 @default.
- W3043633500 cites W2114061607 @default.
- W3043633500 cites W2125743812 @default.
- W3043633500 cites W2136741165 @default.
- W3043633500 cites W2171034745 @default.
- W3043633500 cites W2187594337 @default.
- W3043633500 cites W2272232474 @default.
- W3043633500 cites W2272441223 @default.
- W3043633500 cites W2335086656 @default.
- W3043633500 cites W2470816429 @default.
- W3043633500 cites W2481635640 @default.
- W3043633500 cites W2507157998 @default.
- W3043633500 cites W2510994553 @default.
- W3043633500 cites W2522671493 @default.
- W3043633500 cites W2542174119 @default.
- W3043633500 cites W2558998316 @default.
- W3043633500 cites W2574987849 @default.
- W3043633500 cites W2576586904 @default.
- W3043633500 cites W2621868363 @default.
- W3043633500 cites W2624658198 @default.
- W3043633500 cites W2733062935 @default.
- W3043633500 cites W2749119548 @default.
- W3043633500 cites W2755852674 @default.
- W3043633500 cites W2767641739 @default.
- W3043633500 cites W2770253888 @default.
- W3043633500 cites W2775410943 @default.
- W3043633500 cites W2788567766 @default.
- W3043633500 cites W2790511133 @default.
- W3043633500 cites W2790704802 @default.
- W3043633500 cites W2792471470 @default.
- W3043633500 cites W2800498045 @default.
- W3043633500 cites W2801231312 @default.
- W3043633500 cites W2801619455 @default.
- W3043633500 cites W2802065685 @default.
- W3043633500 cites W2802201493 @default.
- W3043633500 cites W2802280245 @default.
- W3043633500 cites W2802452799 @default.
- W3043633500 cites W2802460418 @default.
- W3043633500 cites W2804303875 @default.
- W3043633500 cites W2805268646 @default.
- W3043633500 cites W2805591174 @default.
- W3043633500 cites W2806143680 @default.
- W3043633500 cites W2810722861 @default.
- W3043633500 cites W2825595711 @default.
- W3043633500 cites W2883502732 @default.
- W3043633500 cites W2885434353 @default.
- W3043633500 cites W2887691089 @default.
- W3043633500 cites W2887891314 @default.
- W3043633500 cites W2894870637 @default.
- W3043633500 cites W2896114205 @default.
- W3043633500 cites W2899350501 @default.
- W3043633500 cites W2903797140 @default.
- W3043633500 cites W2905031012 @default.
- W3043633500 cites W2906505923 @default.
- W3043633500 cites W2909790116 @default.
- W3043633500 cites W2910174562 @default.
- W3043633500 cites W2910372448 @default.
- W3043633500 cites W2919144141 @default.
- W3043633500 cites W2924981021 @default.
- W3043633500 cites W2936440807 @default.
- W3043633500 cites W2938958938 @default.
- W3043633500 cites W2941759180 @default.
- W3043633500 cites W2942186791 @default.
- W3043633500 cites W2945594417 @default.
- W3043633500 cites W2945928836 @default.
- W3043633500 cites W2946729124 @default.
- W3043633500 cites W2955267624 @default.
- W3043633500 cites W2970319046 @default.
- W3043633500 cites W2974609736 @default.
- W3043633500 cites W2975258322 @default.
- W3043633500 cites W2978479372 @default.
- W3043633500 cites W2979096478 @default.
- W3043633500 cites W2986750581 @default.
- W3043633500 cites W3022151129 @default.
- W3043633500 cites W3027081978 @default.
- W3043633500 doi "https://doi.org/10.1016/j.apcatb.2020.119339" @default.
- W3043633500 hasPublicationYear "2020" @default.