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- W3043680922 abstract "Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60% by a general reaction of [Ru(η 5 -C 5 H 5 )(PPh 3 )L] + X − (L = 2,2′-bipyridine or 1,10-phenanthroline, X = Cl or Br) or [Ru(η 5 -C 5 ,H 5 )(PPh 3 )(L)X] (L = PPh 3 , pyridine, 3-picoline, 4-picoline, [Formula: see text], or [Formula: see text]; X − = Cl − , Br − , I − , CN − , NCS − , H − , or SnCl 3 − ) with NOBr 3 and N 2 O 3 . In these complexes NO seems to bind with the metal ion as NO + . The reactions of N 2 O 3 gave either nitrito or nitrosyl dinitrito complexes. The reactions of NOBr 3 with trichlorostannate complexes did not yield nitrosyl complexes, instead nitrito complexes were isolated in which spectroscopic evidence (ir, 1 H nmr) suggest π-interaction of one of the phenyl rings of the triphenylphosphine ligand to the ruthenium center. All products are characterised by elementary microanalyses, conductivity, magnetic moment measurements, electronic, ir, and 1 H nmr spectral data." @default.
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- W3043680922 date "1985-04-01" @default.
- W3043680922 modified "2023-09-27" @default.
- W3043680922 title "Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide" @default.
- W3043680922 doi "https://doi.org/10.1139/v85-160" @default.
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