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• W3044005757 abstract "Self-diffusion in dense rod suspensions are subject to strong geometric constraints because of steric interactions. This topological effect is essentially anisotropic when rods are nematically aligned with their neighbors, raising considerable challenges in understanding and analyzing their impacts on the bulk physical properties. Via a classical Doi-Onsager kinetic model with the Maier-Saupe potential, we characterize the long-time rotational Brownian diffusivity for dense suspensions of hard rods of finite aspect ratios, based on quadratic orientation autocorrelation functions. Furthermore, we show that the computed nonmonotonic scalings of the diffusivity as a function of volume fraction can be accurately predicted by an alternative tube model in the nematic phase." @default.
• W3044005757 created "2020-07-29" @default.
• W3044005757 creator A5036677053 @default.
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• W3044005757 date "2020-07-20" @default.
• W3044005757 modified "2023-10-08" @default.
• W3044005757 title "Scaling law of Brownian rotation in dense hard-rod suspensions" @default.
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• W3044005757 doi "https://doi.org/10.1103/physreve.102.012608" @default.
• W3044005757 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32794925" @default.
• W3044005757 hasPublicationYear "2020" @default.
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