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• W3044011401 abstract "We investigated electroreduction of Ti2+ to metallic titanium in the LiCl–KCl–CsCl system, which has a eutectic point at 263 °C. Cyclic voltammetry was carried out in the TiCl2-saturated LiCl–KCl–CsCl at 300 °C, and the effect of F− addition on the reduction behavior of Ti2+ was investigated. It was revealed that addition of F− increases the limiting current density of electrodeposition of titanium at 300–500 °C. This might be mainly attributed to the increase in total concentration of soluble titanium ions in the molten salt. Then, we demonstrated the electrodeposition of metallic titanium in the LiCl–KCl–CsCl with and without F− at 350 °C. After the electrolysis in F−-added molten salt and acid leaching, LiF remained on the deposited titanium. This is because the solubility of LiF in aqueous solution is quite low. An efficient method to remove LiF is required when F−-added LiCl–KCl–CsCl is used as electrolyte." @default.
• W3044011401 created "2020-07-29" @default.
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• W3044011401 date "2020-08-01" @default.
• W3044011401 modified "2023-10-05" @default.
• W3044011401 title "Low Temperature Electrodeposition of Titanium in Fluoride-Added LiCl–KCl–CsCl Molten Salt" @default.
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• W3044011401 doi "https://doi.org/10.2320/matertrans.mt-m2020083" @default.
• W3044011401 hasPublicationYear "2020" @default.
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