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• W3044156611 endingPage "131416" @default.
• W3044156611 startingPage "131416" @default.
• W3044156611 abstract "The mechanism of solvolysis of cyclopropyl halides and tosylates yielding allylic products is deduced at the molecular level through the Bent Bond/Antiperiplanar Hypothesis (BBAH). The cleavage of the cyclopropane bond occurs in a concerted manner with the departure of the leaving group. This rearrangement takes place when the pyramidal diradical intermediate derived from the structure of the cyclopropane τ bond is antiperiplanar to the halide or sulfonate leaving group." @default.
• W3044156611 created "2020-07-29" @default.
• W3044156611 creator A5007613996 @default.
• W3044156611 date "2020-09-01" @default.
• W3044156611 modified "2023-09-25" @default.
• W3044156611 title "The bent bond / antiperiplanar hypothesis and the thermal rearrangement of cyclopropyl halides and tosylates" @default.
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• W3044156611 doi "https://doi.org/10.1016/j.tet.2020.131416" @default.
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