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• W3044409336 endingPage "118724" @default.
• W3044409336 startingPage "118724" @default.
• W3044409336 abstract "In this work, Sn(II)-exchanged silicotungstic acid salt (i.e., Sn2SiW12O40) was synthesized and evaluated as the catalyst on the acetalization of glycerol with acetone to produce solketal, a versatile bioadditive of fuel. The Sn2SiW12O40 salt was compared to the other solid Keggin heteropoly salts (i.e., Sn3/4PMo12O40, Sn3/4PW12O40), and liquid (i.e., HCl, H2SO4 and p-toluenesulfonic acid) catalysts. Amongst the catalysts assessed, it was the most active, achieving a high conversion (ca. > 99%, after 1 h reaction at room temperature) and selective (ca. 97%) toward the formation of solketal. Moreover, the Sn2SiW12O40 salt demonstrated to be more active than acid and precursor Tin (II) chloride salt, as well as other heteropoly salts and solid supported catalysts. The effects of the main reaction variables were assessed. The Sn(II) cation, as well as the silicotungstate anion, showed being essential to convert glycerol to solketal. Insights on the reaction mechanism were performed. In a simple recycle procedure, the solketal was purified, the acetone excess recycled, and the catalyst was reused without loss activity." @default.
• W3044409336 created "2020-07-29" @default.
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• W3044409336 date "2020-12-01" @default.
• W3044409336 modified "2023-09-30" @default.
• W3044409336 title "An efficient process to synthesize solketal from glycerol over tin (II) silicotungstate catalyst" @default.
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• W3044409336 doi "https://doi.org/10.1016/j.fuel.2020.118724" @default.
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