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- W3044431206 abstract "Abstract Thermoresponsive polymers have emerged as promising candidates for biomedical applications. Seven novel oligoethylene glycol (OEG) functionalized polyvalerolactones P1–P7 are synthesized from poly(α‐allyl‐δ‐valerolactone) via thiol‐ene addition post‐polymerization modification. All seven polymers exhibit thermoresponsive behavior with lower critical solution temperatures (LCSTs) ranging from 13.8 to 92.2 °C. Polymers P5–P7 are synthesized via thiol‐ene addition reaction using two thiol mixtures at three different ratios. LCSTs of P5–P7 fall in between those of P1 and P2 , and exhibit a linear relationship, indicating a tunable thermoresponsive system. This newly developed system offers great control for a desired thermoresponsive biocompatible, biodegradable polymeric system with desired LCSTs." @default.
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- W3044431206 date "2020-07-20" @default.
- W3044431206 modified "2023-09-26" @default.
- W3044431206 title "Facile Synthesis of Novel Thermo‐Responsive Polyvalerolactones with Tunable LCSTs" @default.
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- W3044431206 doi "https://doi.org/10.1002/macp.202000136" @default.
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