Matches in SemOpenAlex for { <https://semopenalex.org/work/W3044487795> ?p ?o ?g. }
- W3044487795 endingPage "117468" @default.
- W3044487795 startingPage "117468" @default.
- W3044487795 abstract "This work aims to take full advantage of ionic liquids’ (ILs) “designer solvent” nature in order to expand the applicability of solid-liquid biphasic systems (SLBS) as alternative chiral resolution techniques. To this purpose, twelve chiral ILs, bearing chirality on the cation or the anion, were used as chiral selectors in SLBS to selectively precipitate mandelic acid enantiomers. The precipitation studies were performed using aqueous solutions of the chiral ILs or their chiral precursors, where the impact of the chemical structure and chirality was investigated. The most efficient chiral ILs were employed to evaluate the influence of different operational conditions on the formed precipitate, namely resolution time, resolution speed, temperature, initial concentration of chiral IL, initial concentration of racemic mandelic acid and water content. When compared to their precursors, chiral ILs showed an enhanced ability to induce enantioselective precipitation. The composition of the precipitate formed, and the molecular-level mechanisms leading to enantioselective precipitation, were also uncovered. Due to cooperative interactions between the chiral IL and the target mandelic acid enantiomer, the [N4444][D-Phe]-based SLBS proposed allowed to obtain maximum enantiomeric excess of 51% in a single-step, without any further additives." @default.
- W3044487795 created "2020-07-29" @default.
- W3044487795 creator A5006457478 @default.
- W3044487795 creator A5023312612 @default.
- W3044487795 creator A5025604282 @default.
- W3044487795 creator A5066792161 @default.
- W3044487795 creator A5086896146 @default.
- W3044487795 creator A5090541369 @default.
- W3044487795 date "2020-12-01" @default.
- W3044487795 modified "2023-10-17" @default.
- W3044487795 title "Separation of mandelic acid enantiomers using solid-liquid biphasic systems with chiral ionic liquids" @default.
- W3044487795 cites W1557141846 @default.
- W3044487795 cites W1724141729 @default.
- W3044487795 cites W1909897406 @default.
- W3044487795 cites W1922431434 @default.
- W3044487795 cites W1967649108 @default.
- W3044487795 cites W1972524792 @default.
- W3044487795 cites W1977618051 @default.
- W3044487795 cites W1988760536 @default.
- W3044487795 cites W1990903481 @default.
- W3044487795 cites W2004944751 @default.
- W3044487795 cites W2009250219 @default.
- W3044487795 cites W2013417542 @default.
- W3044487795 cites W2034911791 @default.
- W3044487795 cites W2041682923 @default.
- W3044487795 cites W2059205366 @default.
- W3044487795 cites W2061674634 @default.
- W3044487795 cites W2066885984 @default.
- W3044487795 cites W2070969790 @default.
- W3044487795 cites W2080079206 @default.
- W3044487795 cites W2082131188 @default.
- W3044487795 cites W2084116993 @default.
- W3044487795 cites W2086080452 @default.
- W3044487795 cites W2087287072 @default.
- W3044487795 cites W2090545574 @default.
- W3044487795 cites W2131694708 @default.
- W3044487795 cites W2154908503 @default.
- W3044487795 cites W2159691823 @default.
- W3044487795 cites W2160141374 @default.
- W3044487795 cites W2314420863 @default.
- W3044487795 cites W2333520560 @default.
- W3044487795 cites W2469855847 @default.
- W3044487795 cites W2529415253 @default.
- W3044487795 cites W2560334893 @default.
- W3044487795 cites W2584163328 @default.
- W3044487795 cites W2584915193 @default.
- W3044487795 cites W2889738317 @default.
- W3044487795 cites W2899131905 @default.
- W3044487795 cites W2913078746 @default.
- W3044487795 cites W2921385696 @default.
- W3044487795 cites W2951597352 @default.
- W3044487795 cites W2975073502 @default.
- W3044487795 cites W4232277213 @default.
- W3044487795 doi "https://doi.org/10.1016/j.seppur.2020.117468" @default.
- W3044487795 hasPublicationYear "2020" @default.
- W3044487795 type Work @default.
- W3044487795 sameAs 3044487795 @default.
- W3044487795 citedByCount "11" @default.
- W3044487795 countsByYear W30444877952021 @default.
- W3044487795 countsByYear W30444877952022 @default.
- W3044487795 countsByYear W30444877952023 @default.
- W3044487795 crossrefType "journal-article" @default.
- W3044487795 hasAuthorship W3044487795A5006457478 @default.
- W3044487795 hasAuthorship W3044487795A5023312612 @default.
- W3044487795 hasAuthorship W3044487795A5025604282 @default.
- W3044487795 hasAuthorship W3044487795A5066792161 @default.
- W3044487795 hasAuthorship W3044487795A5086896146 @default.
- W3044487795 hasAuthorship W3044487795A5090541369 @default.
- W3044487795 hasBestOaLocation W30444877952 @default.
- W3044487795 hasConcept C107054158 @default.
- W3044487795 hasConcept C121332964 @default.
- W3044487795 hasConcept C124668440 @default.
- W3044487795 hasConcept C127413603 @default.
- W3044487795 hasConcept C146686406 @default.
- W3044487795 hasConcept C153294291 @default.
- W3044487795 hasConcept C154881586 @default.
- W3044487795 hasConcept C156217769 @default.
- W3044487795 hasConcept C161790260 @default.
- W3044487795 hasConcept C163845019 @default.
- W3044487795 hasConcept C16838498 @default.
- W3044487795 hasConcept C178790620 @default.
- W3044487795 hasConcept C184651966 @default.
- W3044487795 hasConcept C185592680 @default.
- W3044487795 hasConcept C20621625 @default.
- W3044487795 hasConcept C21951064 @default.
- W3044487795 hasConcept C2778735290 @default.
- W3044487795 hasConcept C2780471494 @default.
- W3044487795 hasConcept C28173026 @default.
- W3044487795 hasConcept C42360764 @default.
- W3044487795 hasConcept C47849319 @default.
- W3044487795 hasConcept C486523 @default.
- W3044487795 hasConcept C52233224 @default.
- W3044487795 hasConcept C62520636 @default.
- W3044487795 hasConceptScore W3044487795C107054158 @default.
- W3044487795 hasConceptScore W3044487795C121332964 @default.
- W3044487795 hasConceptScore W3044487795C124668440 @default.
- W3044487795 hasConceptScore W3044487795C127413603 @default.
- W3044487795 hasConceptScore W3044487795C146686406 @default.