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• W3044589002 abstract "Two tetranuclear zinc complexes 2a and 2b bearing tridentate N-alkoxide ketoiminate ligands have been synthesized and fully characterized by single-crystal X-ray structure analysis, NMR spectroscopy together with elemental analyses. Both of 2a and 2b can act as active catalysts in the ring-opening polymerization (ROP) of racemic-lactide (rac-LA) without additional co-initiators, either in solution or under industrially preferred melt conditions (130 °C no solvent). To be noted, 2a and 2b show remarkable activities for bulk rac-LA polymerization even with low catalyst loading of 0.1 mol%, yielding polymers with high molecular weights (Mn) of up to 91,200 g/mol (2b), and very high turnover frequencies (TOF) of 19,000 h−1 (2b) and 19,800 h−1 (2a)." @default.
• W3044589002 created "2020-07-29" @default.
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• W3044589002 date "2020-09-01" @default.
• W3044589002 modified "2023-10-16" @default.
• W3044589002 title "Syntheses, structures and catalysis of tetranuclear zinc N-alkoxide ketoiminate complexes for ring-opening polymerization of rac-lactide" @default.
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• W3044589002 doi "https://doi.org/10.1016/j.inoche.2020.108136" @default.
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