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- W3044593971 abstract "Transition-metal-catalyzed hydroalkylation of alkenes with 1,3-dicarbonyl compounds is a useful reaction to construct a C–C bond under neutral reaction conditions in a highly atom-economical manner. We found that hydroalkylation of aliphatic alkenes with β-ketoesters proceeded with the use of a cationic iridium complex and bidentate phosphine ligand to give selectively branched α-substituted β-ketoesters in high yields. The obtained hydroalkylated compounds can be converted to β-substituted ketones through one-pot Krapcho dealkoxycarbonylation." @default.
- W3044593971 created "2020-07-29" @default.
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- W3044593971 date "2020-07-22" @default.
- W3044593971 modified "2023-10-10" @default.
- W3044593971 title "Iridium-Catalyzed Hydroalkylation of Aliphatic Alkenes with β-Ketoesters: Formal Hydroalkylation with Methyl Ketones" @default.
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- W3044593971 doi "https://doi.org/10.1021/acs.orglett.0c02291" @default.
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