FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3044754111> ?p ?o ?g. }

• W3044754111 endingPage "9442" @default.
• W3044754111 startingPage "9436" @default.
• W3044754111 abstract "Enormous efforts have been devoted to the development of crystalline aerogels toward heterogeneous catalysis, energy storage, ion/molecular absorption, and luminescence. However, properties of aerogels are not fully exploited due to their low content of functional moieties embedded in their solid networks, low crystallinity, and limited chemical compositions. Herein, we develop a one-pot approach based on crystallization from amorphous metal hydroxides modified with a β-diketone ligand, toward crystalline transition-metal hydroxide aerogels. Synthesis of monolithic and crystalline aerogels of layered double hydroxide (LDH) was performed in a Ni–Al system starting from aqueous ethanol solutions of NiCl2·6H2O and AlCl3·6H2O with acetylacetone (acac) as an organic ligand. Propylene oxide (PO) as an alkalization reagent was added into precursory solutions to yield monolithic wet gels. The successive pH increase induces the formation of a three-dimensional (3-D) solid framework composed of amorphous Al(OH)3. Then, amphoteric Al(OH)3 undergoes crystallization into Ni–Al LDH via an acetylacetone-driven dissolution–crystallization of metal hydroxides without destroying the preformed 3-D solid framework. The process allows us to obtain crystalline aerogel monoliths with high porosity and high transparency after supercritical CO2 drying of wet gels. The present scheme can be expected to synthesize functionalized aerogel composed of crystalline transition-metal oxide/hydroxide nanobuilding blocks (NBBs)." @default.
• W3044754111 created "2020-07-29" @default.
• W3044754111 creator A5017812441 @default.
• W3044754111 creator A5019483142 @default.
• W3044754111 creator A5022541474 @default.
• W3044754111 creator A5046866647 @default.
• W3044754111 creator A5051853768 @default.
• W3044754111 creator A5065240003 @default.
• W3044754111 creator A5073108559 @default.
• W3044754111 creator A5075999552 @default.
• W3044754111 creator A5088511289 @default.
• W3044754111 date "2020-07-20" @default.
• W3044754111 modified "2023-10-08" @default.
• W3044754111 title "Synthesis of a Crystalline and Transparent Aerogel Composed of Ni–Al Layered Double Hydroxide Nanoparticles through Crystallization from Amorphous Hydrogel" @default.
• W3044754111 cites W1528646947 @default.
• W3044754111 cites W1966257485 @default.
• W3044754111 cites W1967471639 @default.
• W3044754111 cites W1998626888 @default.
• W3044754111 cites W2003063846 @default.
• W3044754111 cites W2006010064 @default.
• W3044754111 cites W2007806750 @default.
• W3044754111 cites W2034969239 @default.
• W3044754111 cites W2040810350 @default.
• W3044754111 cites W2042646188 @default.
• W3044754111 cites W2048953780 @default.
• W3044754111 cites W2050497584 @default.
• W3044754111 cites W2051194659 @default.
• W3044754111 cites W2052070060 @default.
• W3044754111 cites W2052785222 @default.
• W3044754111 cites W2061342509 @default.
• W3044754111 cites W2063871481 @default.
• W3044754111 cites W2073380453 @default.
• W3044754111 cites W2081236420 @default.
• W3044754111 cites W2081914049 @default.
• W3044754111 cites W2088713963 @default.
• W3044754111 cites W2088763701 @default.
• W3044754111 cites W2090324373 @default.
• W3044754111 cites W2104098734 @default.
• W3044754111 cites W2105044498 @default.
• W3044754111 cites W2117014051 @default.
• W3044754111 cites W2132317725 @default.
• W3044754111 cites W2142979065 @default.
• W3044754111 cites W2151861346 @default.
• W3044754111 cites W2237686437 @default.
• W3044754111 cites W2317303289 @default.
• W3044754111 cites W2332801266 @default.
• W3044754111 cites W2334928601 @default.
• W3044754111 cites W2343713950 @default.
• W3044754111 cites W2533020209 @default.
• W3044754111 cites W2584731085 @default.
• W3044754111 cites W2752931097 @default.
• W3044754111 cites W2775201533 @default.
• W3044754111 cites W2883573047 @default.
• W3044754111 cites W2966138176 @default.
• W3044754111 cites W3096986715 @default.
• W3044754111 doi "https://doi.org/10.1021/acs.langmuir.0c01292" @default.
• W3044754111 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32683867" @default.
• W3044754111 hasPublicationYear "2020" @default.
• W3044754111 type Work @default.
• W3044754111 sameAs 3044754111 @default.
• W3044754111 citedByCount "3" @default.
• W3044754111 countsByYear W30447541112021 @default.
• W3044754111 countsByYear W30447541112023 @default.
• W3044754111 crossrefType "journal-article" @default.
• W3044754111 hasAuthorship W3044754111A5017812441 @default.
• W3044754111 hasAuthorship W3044754111A5019483142 @default.
• W3044754111 hasAuthorship W3044754111A5022541474 @default.
• W3044754111 hasAuthorship W3044754111A5046866647 @default.
• W3044754111 hasAuthorship W3044754111A5051853768 @default.
• W3044754111 hasAuthorship W3044754111A5065240003 @default.
• W3044754111 hasAuthorship W3044754111A5073108559 @default.
• W3044754111 hasAuthorship W3044754111A5075999552 @default.
• W3044754111 hasAuthorship W3044754111A5088511289 @default.
• W3044754111 hasConcept C127413603 @default.
• W3044754111 hasConcept C155672457 @default.
• W3044754111 hasConcept C159985019 @default.
• W3044754111 hasConcept C171250308 @default.
• W3044754111 hasConcept C178790620 @default.
• W3044754111 hasConcept C179104552 @default.
• W3044754111 hasConcept C184651966 @default.
• W3044754111 hasConcept C185592680 @default.
• W3044754111 hasConcept C191897082 @default.
• W3044754111 hasConcept C192562407 @default.
• W3044754111 hasConcept C203036418 @default.
• W3044754111 hasConcept C2775896084 @default.
• W3044754111 hasConcept C2779851234 @default.
• W3044754111 hasConcept C2780002320 @default.
• W3044754111 hasConcept C2780012831 @default.
• W3044754111 hasConcept C40875361 @default.
• W3044754111 hasConcept C42360764 @default.
• W3044754111 hasConcept C46275449 @default.
• W3044754111 hasConcept C56052488 @default.
• W3044754111 hasConcept C88380143 @default.
• W3044754111 hasConceptScore W3044754111C127413603 @default.
• W3044754111 hasConceptScore W3044754111C155672457 @default.
• W3044754111 hasConceptScore W3044754111C159985019 @default.
• W3044754111 hasConceptScore W3044754111C171250308 @default.
• W3044754111 hasConceptScore W3044754111C178790620 @default.

• next