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• W3044763933 endingPage "5853" @default.
• W3044763933 startingPage "5843" @default.
• W3044763933 abstract "Homochiral coordination polymers have emerged as promising candidates for a range of chirotechnological applications, including asymmetric catalysis and enantioselective separation. The use of ligands derived from naturally occurring l-amino acids is an inexpensive and effective approach for generating a range of homochiral coordination polymers. To investigate the structure-directing effect of the amino acid side chain, seven homochiral Cd(II) frameworks were synthesized using semirigid dicarboxylates composed of l-amino acids appended to terephthalic acid (H2TMXxx, where Xxx = Ala, Val, Phe, Trp, Tyr, and His) and bis(4-pyridyl)ethylene coligands. When Xxx = Val, Tyr, Phe, or Trp, a series of 2D (4,4)-networks were obtained, in which the different intermolecular interactions of the side chains result in subtle changes in crystal packing. Employing Xxx = Ala or Tyr led to 3D frameworks with a {65·8} topology, in which the varying steric bulk of the side chains results in significant differences in framework geometry as well as the shape and volume of the solvent-accessible channels. When Xxx = His, the imidazole side chains coordinate to the metal center to direct the formation of a 3D pillared structure that undergoes 2-fold interpenetration." @default.
• W3044763933 created "2020-07-29" @default.
• W3044763933 creator A5015741289 @default.
• W3044763933 creator A5032342085 @default.
• W3044763933 date "2020-07-21" @default.
• W3044763933 modified "2023-10-03" @default.
• W3044763933 title "Chiral Cd(II) Coordination Polymers Based on Amino Acid Derivatives: The Effect of Side Chain on Structure" @default.
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• W3044763933 doi "https://doi.org/10.1021/acs.cgd.0c00468" @default.
• W3044763933 hasPublicationYear "2020" @default.
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