FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3044863256> ?p ?o ?g. }

• W3044863256 endingPage "6319" @default.
• W3044863256 startingPage "6312" @default.
• W3044863256 abstract "We report the X-ray crystal structure of the Au30–xAgx(S-tBu)18 alloy and the effect of the ligand on alloying site preferences. Gold–silver nanoalloys prepared by co-reduction of metal salts are known to have only partial Ag occupancies. Interestingly, Au30–xAgx(S-tBu)18 has 100% Ag occupancy at two sites on the core surface as well as partial Ag occupancies on the surface, capping, and staples sites. The Au30–xAgx(S-tBu)18 (x = 1–5) composition was confirmed by X-ray diffraction and electrospray ionization mass spectrometry studies. Thiolate ligands can be categorized into three classes on the basis of the groups at the α-position as aliphatic, aromatic, and bulky thiols. The effect of the ligand on Ag doping can be clearly seen in the crystal structures of Au36–xAgx(SPh-tBu)24 and Au38–xAgx(SCH2CH2Ph)24 when compared with that of Au30–xAgx(S-tBu)18. Ag is preferentially doped onto the core surface when the ligand is aliphatic, and Ag is doped in both core surface and staple metal sites when the ligand is aromatic or bulky." @default.
• W3044863256 created "2020-07-29" @default.
• W3044863256 creator A5013133600 @default.
• W3044863256 creator A5038153908 @default.
• W3044863256 creator A5038931310 @default.
• W3044863256 creator A5091688759 @default.
• W3044863256 date "2020-07-23" @default.
• W3044863256 modified "2023-10-16" @default.
• W3044863256 title "Crystal Structure of Au_{30–<i>x</i>}Ag_<i>x</i>(S-<i>t</i>Bu)₁₈ and Effect of the Ligand on Ag Alloying in Gold Nanomolecules" @default.
• W3044863256 cites W1129730006 @default.
• W3044863256 cites W1969360633 @default.
• W3044863256 cites W1973877929 @default.
• W3044863256 cites W1978634069 @default.
• W3044863256 cites W1982981507 @default.
• W3044863256 cites W1988659705 @default.
• W3044863256 cites W2004370951 @default.
• W3044863256 cites W2005034587 @default.
• W3044863256 cites W2020451212 @default.
• W3044863256 cites W2021713080 @default.
• W3044863256 cites W2031495063 @default.
• W3044863256 cites W2041036661 @default.
• W3044863256 cites W2046075398 @default.
• W3044863256 cites W2047717063 @default.
• W3044863256 cites W2049540112 @default.
• W3044863256 cites W2050307916 @default.
• W3044863256 cites W2054603000 @default.
• W3044863256 cites W2059205366 @default.
• W3044863256 cites W2065075767 @default.
• W3044863256 cites W2072658955 @default.
• W3044863256 cites W2076898190 @default.
• W3044863256 cites W2081185606 @default.
• W3044863256 cites W2099992615 @default.
• W3044863256 cites W2101547779 @default.
• W3044863256 cites W2118647094 @default.
• W3044863256 cites W2131846706 @default.
• W3044863256 cites W2132454074 @default.
• W3044863256 cites W2164473519 @default.
• W3044863256 cites W2244570801 @default.
• W3044863256 cites W2269323211 @default.
• W3044863256 cites W2287768545 @default.
• W3044863256 cites W2294058254 @default.
• W3044863256 cites W2297573337 @default.
• W3044863256 cites W2299698922 @default.
• W3044863256 cites W2313077988 @default.
• W3044863256 cites W2314706128 @default.
• W3044863256 cites W2317068287 @default.
• W3044863256 cites W2320187489 @default.
• W3044863256 cites W2326957983 @default.
• W3044863256 cites W2328991736 @default.
• W3044863256 cites W2332325803 @default.
• W3044863256 cites W2341803941 @default.
• W3044863256 cites W2753844621 @default.
• W3044863256 cites W2806886459 @default.
• W3044863256 cites W2808210868 @default.
• W3044863256 cites W2808314597 @default.
• W3044863256 cites W2886428681 @default.
• W3044863256 cites W2899153793 @default.
• W3044863256 cites W2922449693 @default.
• W3044863256 cites W2945677369 @default.
• W3044863256 cites W2989938638 @default.
• W3044863256 cites W2995618854 @default.
• W3044863256 cites W3000160491 @default.
• W3044863256 cites W3104813340 @default.
• W3044863256 cites W4234750540 @default.
• W3044863256 doi "https://doi.org/10.1021/acs.jpclett.0c01330" @default.
• W3044863256 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32700914" @default.
• W3044863256 hasPublicationYear "2020" @default.
• W3044863256 type Work @default.
• W3044863256 sameAs 3044863256 @default.
• W3044863256 citedByCount "7" @default.
• W3044863256 countsByYear W30448632562021 @default.
• W3044863256 countsByYear W30448632562023 @default.
• W3044863256 crossrefType "journal-article" @default.
• W3044863256 hasAuthorship W3044863256A5013133600 @default.
• W3044863256 hasAuthorship W3044863256A5038153908 @default.
• W3044863256 hasAuthorship W3044863256A5038931310 @default.
• W3044863256 hasAuthorship W3044863256A5091688759 @default.
• W3044863256 hasConcept C115624301 @default.
• W3044863256 hasConcept C116569031 @default.
• W3044863256 hasConcept C162356407 @default.
• W3044863256 hasConcept C170493617 @default.
• W3044863256 hasConcept C178790620 @default.
• W3044863256 hasConcept C185592680 @default.
• W3044863256 hasConcept C192562407 @default.
• W3044863256 hasConcept C199360897 @default.
• W3044863256 hasConcept C2781285689 @default.
• W3044863256 hasConcept C40684141 @default.
• W3044863256 hasConcept C41008148 @default.
• W3044863256 hasConcept C43617362 @default.
• W3044863256 hasConcept C49040817 @default.
• W3044863256 hasConcept C544153396 @default.
• W3044863256 hasConcept C55493867 @default.
• W3044863256 hasConcept C57863236 @default.
• W3044863256 hasConcept C71240020 @default.
• W3044863256 hasConcept C73922627 @default.
• W3044863256 hasConcept C8010536 @default.
• W3044863256 hasConceptScore W3044863256C115624301 @default.
• W3044863256 hasConceptScore W3044863256C116569031 @default.

• next